The development of new or more sustainable, active, efficient, controlled, and selective
polymerization reactions or processes continues to be crucial for the synthesis of important …

The manipulation of amino C–H bonds has garnered significant interest from the synthetic
community due to its inherently high atom, step and redox economy. This Tutorial Review …

Ten years have passed since the conception of what was termed Lewis pair polymerization
(LPP) that employs Lewis acid and base in pairs to not only activate monomers but also …

The scientific community has witnessed extensive developments and applications of
organoboron compounds as synthetic elements and metal-free catalysts for the construction …

This contribution reports the first example of highly selective reduction of CO2 into CH4 via
tandem hydrosilylation with mixed main-group organo-Lewis acid (LA) catalysts [Al (C6F5) …

α-Methylene-γ-butyrolactone (MBL), a naturally occurring and biomass-sourced bifunctional
monomer, contains both a highly reactive exocyclic C C bond and a highly stable five …

To prepare biobased polymers, particular attention must be paid to the obtention of the
monomers from which they are derived.(Meth) acrylates and their analogs constitute such a …

An efficient catalytic method to convert an α-C–H bond of N-alkylamines into an α-C–alkynyl
bond was developed. In the past, such transformations were carried out under oxidative …

The living polymerization of conjugated polar alkenes such as methacrylates by a
noninteracting, authentic frustrated Lewis pair (FLP) has remained elusive ever since the …

Lewis pair polymerization (LPP) has emerged as a powerful tool for the efficient
polymerization of polar vinyl monomers. However, air/moisture, highly sensitive metal-based …