The interest in functional supramolecular systems for the design of innovative materials and
technologies, able to fundamentally change the world, is growing at a high pace. The huge …

Polyoxometalates (POMs) are a series of molecular metal oxide clusters, which span the two
domains of solutes and solid metal oxides. The unique characters of POMs in structure …

Osteosarcoma is one of the most dreadful bone neoplasms in young people, necessitating
the development of innovative therapies that can effectively eliminate tumors while …

A series of remarkable crystalline compounds [Cu2 (BTC) 4/3 (H2O) 2] 6 [H n
XM12O40]·(C4H12N) 2 (X= Si, Ge, P, As; M= W, Mo) were obtained from the simple one …

Large, hydrophilic polyoxoanions with high solubility in water and/or other polar solvents
demonstrate unique solution behavior by self-assembling into single layer, hollow, spherical …

Following Nature's lessons, today chemists can cross the boundary of the small molecule
world to construct multifunctional and highly complex molecular nano-objects up to protein …

Functionalization via covalent grafting of organic functions allows to tune the redox and acid–
base properties, and the solubility of polyoxometalates, to enhance their stability and …

Polyoxometalate molybdenum blue (MB) complexes typically exist as discrete multianionic
clusters and are composed of repeating Mo building units. MB wheels such as {Mo176} and …

Large, hydrophilic inorganic ions (mostly polyoxometalate macroions and cationic metal−
organic hybrid nanocages) with high solubility in water and/or other polar solvents …

Polyoxometalates (POMs) are robust, discrete, and structurally well-defined metal-oxide
cluster anions that have stimulated research in broad fields of sciences. Keplerates, as …