Proton Relays in Molecular Catalysis for Hydrogen Evolution and Oxidation: Lessons From the Mimicry of Hydrogenases and Electrochemical Kinetic Analyses
M Haake, B Reuillard… - Angewandte Chemie …, 2024 - Wiley Online Library
The active sites of metalloenzymes involved in small molecules activation often contain
pendant bases that act as proton relay promoting proton‐coupled electron‐transfer …
pendant bases that act as proton relay promoting proton‐coupled electron‐transfer …
Hydrolysis and Transfer Reactivity of the Coordinated Thiolate, Thiocarboxylate, and Selenolate in Binuclear Zinc (II) Complexes
A new binuclear Zn (II) complex,[Zn2 (PhBIMP)(DMF) 2] 3+(1)(where PhBIMP1 is the anion
of 2, 6-bis [bis [(N-1-methyl-4, 5-diphenylimidazoylmethyl) amino] methyl]-4-methylphenol) …
of 2, 6-bis [bis [(N-1-methyl-4, 5-diphenylimidazoylmethyl) amino] methyl]-4-methylphenol) …
Tuning the charge transport property and photocatalytic activity of anthracene-based 1D π–d conjugated coordination polymers by interlayer stacking
One-dimensional (1D) π–d-conjugated coordination polymers (CCPs) with charge
delocalization have attracted significant attention due to their potential application in energy …
delocalization have attracted significant attention due to their potential application in energy …
Electrocatalytic CO2 Reduction to Formate with Molecular Fe(III) Complexes Containing Pendent Proton Relays
Previously, we reported an iron (III) complex with 6, 6′-([2, 2′-bipyridine]-6, 6′-diyl) bis
(2, 4-ditertbutyl-phenol) as a ligand (Fe (tbudhbpy) Cl, 1) as catalytically competent for the …
(2, 4-ditertbutyl-phenol) as a ligand (Fe (tbudhbpy) Cl, 1) as catalytically competent for the …
Electrocatalytic reduction of dioxygen to hydrogen peroxide by a molecular manganese complex with a bipyridine-containing schiff base ligand
The synthesis and electrocatalytic reduction of dioxygen by a molecular manganese (III)
complex with a tetradentate dianionic bipyridine-based ligand is reported. Electrochemical …
complex with a tetradentate dianionic bipyridine-based ligand is reported. Electrochemical …
Biohybrid Systems for Improved Bioinspired, Energy‐Relevant Catalysis
Biomimetic catalysts, ranging from small‐molecule metal complexes to supramolecular
assembles, possess many exciting properties that could address salient challenges in …
assembles, possess many exciting properties that could address salient challenges in …
Isolation of monomeric copper (ii) phenolate selenoether complexes using chelating ortho-bisphenylselenide-phenolate ligands and their electrocatalytic hydrogen …
A series of novel copper (II) phenolate selenoether complexes have been synthesized and
structurally characterized for the first time from copper (I) phenanthroline and various …
structurally characterized for the first time from copper (I) phenanthroline and various …
Polymeric coatings for applications in electrocatalytic and photoelectrosynthetic fuel production
Applications of polymeric coatings have emerged as a promising direction for preparing
multilayered assemblies and controlling surface properties. In addition to providing a …
multilayered assemblies and controlling surface properties. In addition to providing a …
Redox mediators accelerate electrochemically-driven solubility cycling of molecular transition metal complexes
The solubility of molecular transition metal complexes can vary widely across different redox
states, leaving these compounds vulnerable to electron transfer-initiated heterogenization …
states, leaving these compounds vulnerable to electron transfer-initiated heterogenization …
Photocatalytic hydrogen production with alkylated nickel bis-dithiolene complexes
Herein, we present the preparation and characterization of two nickel dithiolene complexes,
namely [Ni (C 3 {S 2 C 2 Ph 2} 2)](1) and [Ni (C 3 {p-OMe-C 6 H 4} 2)](2). X-ray diffraction …
namely [Ni (C 3 {S 2 C 2 Ph 2} 2)](1) and [Ni (C 3 {p-OMe-C 6 H 4} 2)](2). X-ray diffraction …