Heterogeneous catalysis for olefin polymerization is one of the most relevant industrial
processes in terms of worldwide diffusion, material volume, and economic turnover. At the …

Heterogeneous catalysts are complex materials, often containing multiple atomic species
and phases with various degrees of structural order. The identification of structure …

The role of the pore architecture of the Ziegler-Natta (ZN) catalysts in the propylene
polymerizations is unveiled, towards the catalyst activity, H 2–and comonomer-response …

Although the formation of nanosized and defective δ-MgCl2 is essential for the performance
of Ziegler–Natta catalysts, the process has not sufficiently been elucidated due to certain …

This study undertakes a thorough computational exploration of Ziegler–Natta catalysis,
emphasizing the role of external donors, particularly dicyclopentyldimethoxysilane (D …

The aim of this work is to investigate the influence of the ethanol content of adducts on the
catalytic behavior of related Ziegler–Natta (ZN) catalysts in propylene homo-and …

Being the main responsible for the huge production of polyolefins, heterogeneous Ziegler-
Natta catalysts are among the most important catalysts in the chemical industry and they …

Heterogeneous Ziegler–Natta propylene polymerization catalysts are today responsible for
the production of over 90% of polypropylene worldwide. These catalysts comprise an …

Abstract Although Ziegler-Natta catalysts were discovered more than four decades ago,
many aspects of their characteristics are not fully understood. The effect of the support …

Abstract Heterogeneous Ziegler-Natta catalysts are promising targets in rapidly growing
polyolefin sector. The progressive developments in catalyst evolution are majorly attributed …