Glass transition of polymers in bulk, confined geometries, and near interfaces

S Napolitano, E Glynos, NB Tito - Reports on Progress in Physics, 2017 - iopscience.iop.org
When cooled or pressurized, polymer melts exhibit a tremendous reduction in molecular
mobility. If the process is performed at a constant rate, the structural relaxation time of the …

Confined crystallization of polymeric materials

RM Michell, AJ Müller - Progress in Polymer Science, 2016 - Elsevier
The interest in confined crystallization has greatly increased with the development and
progress of nanotechnology applications. Polymeric confined crystallization has been …

Vertically aligned and continuous nanoscale ceramic–polymer interfaces in composite solid polymer electrolytes for enhanced ionic conductivity

X Zhang, J **e, F Shi, D Lin, Y Liu, W Liu, A Pei… - Nano …, 2018 - ACS Publications
Among all solid electrolytes, composite solid polymer electrolytes, comprised of polymer
matrix and ceramic fillers, garner great interest due to the enhancement of ionic conductivity …

Soft matter in hard confinement: phase transition thermodynamics, structure, texture, diffusion and flow in nanoporous media

P Huber - Journal of Physics: Condensed Matter, 2015 - iopscience.iop.org
Spatial confinement in nanoporous media affects the structure, thermodynamics and mobility
of molecular soft matter often markedly. This article reviews thermodynamic equilibrium …

Confined crystallization of polymers within nanopores

G Liu, AJ Muller, D Wang - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Crystallization of polymeric materials under nanoscopic confinement is highly
relevant for nanotechnology applications. When a polymer is confined within rigid …

Stiffness variable polymers comprising phase‐changing side‐chains: material syntheses and application explorations

M Gao, Y Meng, C Shen, Q Pei - Advanced Materials, 2022 - Wiley Online Library
Stiffness variable materials have been applied in a variety of engineering fields that require
adaptation, automatic modulation, and morphing because of their unique property to switch …

[HTML][HTML] Fractionated crystallization in semicrystalline polymers

L Sangroniz, B Wang, Y Su, G Liu, D Cavallo… - Progress in Polymer …, 2021 - Elsevier
The crystallization of heterogeneously nucleated bulk polymers typically occurs in a single
exothermic process, within a narrow temperature range, ie, a single exothermic peak is …

A review on the progress of polymer nanostructures with modulated morphologies and properties, using nanoporous AAO templates

C Mijangos, R Hernández, J Martin - Progress in Polymer Science, 2016 - Elsevier
Polymers with the same chemical composition can provide different properties by reducing
the dimension or simply by altering their nanostructure. The recent literature reports …

[HTML][HTML] Confinement effects on polymer crystallization: From droplets to alumina nanopores

RM Michell, I Blaszczyk-Lezak, C Mijangos, AJ Müller - Polymer, 2013 - Elsevier
We review previous works on polymer confined crystallization employing strategies that
allow confinement to go from the micron to the nanometer scale: droplets, blends, block …

Homogeneous crystal nucleation in polymers

C Schick, R Androsch… - Journal of Physics …, 2017 - iopscience.iop.org
The pathway of crystal nucleation significantly influences the structure and properties of
semi-crystalline polymers. Crystal nucleation is normally heterogeneous at low …