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Glass transition of polymers in bulk, confined geometries, and near interfaces
When cooled or pressurized, polymer melts exhibit a tremendous reduction in molecular
mobility. If the process is performed at a constant rate, the structural relaxation time of the …
mobility. If the process is performed at a constant rate, the structural relaxation time of the …
Confined crystallization of polymeric materials
The interest in confined crystallization has greatly increased with the development and
progress of nanotechnology applications. Polymeric confined crystallization has been …
progress of nanotechnology applications. Polymeric confined crystallization has been …
Vertically aligned and continuous nanoscale ceramic–polymer interfaces in composite solid polymer electrolytes for enhanced ionic conductivity
Among all solid electrolytes, composite solid polymer electrolytes, comprised of polymer
matrix and ceramic fillers, garner great interest due to the enhancement of ionic conductivity …
matrix and ceramic fillers, garner great interest due to the enhancement of ionic conductivity …
Soft matter in hard confinement: phase transition thermodynamics, structure, texture, diffusion and flow in nanoporous media
P Huber - Journal of Physics: Condensed Matter, 2015 - iopscience.iop.org
Spatial confinement in nanoporous media affects the structure, thermodynamics and mobility
of molecular soft matter often markedly. This article reviews thermodynamic equilibrium …
of molecular soft matter often markedly. This article reviews thermodynamic equilibrium …
Confined crystallization of polymers within nanopores
Conspectus Crystallization of polymeric materials under nanoscopic confinement is highly
relevant for nanotechnology applications. When a polymer is confined within rigid …
relevant for nanotechnology applications. When a polymer is confined within rigid …
Stiffness variable polymers comprising phase‐changing side‐chains: material syntheses and application explorations
Stiffness variable materials have been applied in a variety of engineering fields that require
adaptation, automatic modulation, and morphing because of their unique property to switch …
adaptation, automatic modulation, and morphing because of their unique property to switch …
[HTML][HTML] Fractionated crystallization in semicrystalline polymers
The crystallization of heterogeneously nucleated bulk polymers typically occurs in a single
exothermic process, within a narrow temperature range, ie, a single exothermic peak is …
exothermic process, within a narrow temperature range, ie, a single exothermic peak is …
A review on the progress of polymer nanostructures with modulated morphologies and properties, using nanoporous AAO templates
Polymers with the same chemical composition can provide different properties by reducing
the dimension or simply by altering their nanostructure. The recent literature reports …
the dimension or simply by altering their nanostructure. The recent literature reports …
[HTML][HTML] Confinement effects on polymer crystallization: From droplets to alumina nanopores
We review previous works on polymer confined crystallization employing strategies that
allow confinement to go from the micron to the nanometer scale: droplets, blends, block …
allow confinement to go from the micron to the nanometer scale: droplets, blends, block …
Homogeneous crystal nucleation in polymers
C Schick, R Androsch… - Journal of Physics …, 2017 - iopscience.iop.org
The pathway of crystal nucleation significantly influences the structure and properties of
semi-crystalline polymers. Crystal nucleation is normally heterogeneous at low …
semi-crystalline polymers. Crystal nucleation is normally heterogeneous at low …