What do 3d-4f butterflies tell us?
Y Peng, AK Powell - Coordination Chemistry Reviews, 2021 - Elsevier
The most studied examples of 3d-4f based single molecule magnets (SMMs) and their
coordination cluster counterparts is that of the 3d-4f butterfly systems which provide a test …
coordination cluster counterparts is that of the 3d-4f butterfly systems which provide a test …
Cantilever torque magnetometry on coordination compounds: from theory to experiments
M Perfetti - Coordination Chemistry Reviews, 2017 - Elsevier
Abstract Cantilever Torque Magnetometry (CTM) is one of the leading techniques to deeply
understand magnetic anisotropy of coordination compounds. The knowledge of magnetic …
understand magnetic anisotropy of coordination compounds. The knowledge of magnetic …
Magnetic Bistability in a Submonolayer of Sublimated Fe4 Single-Molecule Magnets
We demonstrate that Fe4 molecules can be deposited on gold by thermal sublimation in
ultra-high vacuum with retention of single molecule magnet behavior. A magnetic hysteresis …
ultra-high vacuum with retention of single molecule magnet behavior. A magnetic hysteresis …
Propeller‐Shaped Fe4 and Fe3M Molecular Nanomagnets: A Journey from Crystals to Addressable Single Molecules
This Microreview covers the preparation and investigation of Fe4 and Fe3M complexes with
a propeller‐like structure, most of which function as single‐molecule magnets (SMMs). The …
a propeller‐like structure, most of which function as single‐molecule magnets (SMMs). The …
Advances in lanthanide single-ion magnets
We present an overview of the investigation methods of lanthanide-based single-ion
magnet. The electronic structure of lanthanide ions is described in the picture of electron …
magnet. The electronic structure of lanthanide ions is described in the picture of electron …
Probing the Origin of Magnetic Anisotropy in a Dinuclear {MnIIICuII} Single‐Molecule Magnet: The Role of Exchange Anisotropy
Using ab initio calculations all the components of the magnetic anisotropy in a dinuclear
[MnIIICuIICl (5‐Br‐sap) 2 (MeOH)] single‐molecule magnet (SMM) have been computed …
[MnIIICuIICl (5‐Br‐sap) 2 (MeOH)] single‐molecule magnet (SMM) have been computed …
The solvent effect in an axially symmetric Fe III 4 single-molecule magnet
A pair of enantiopure FeIII4 SMMs with axial symmetry was synthesized and characterized
by magnetization and high-frequency electron paramagnetic resonance methods. The …
by magnetization and high-frequency electron paramagnetic resonance methods. The …
Spectroscopy methods for molecular nanomagnets
This chapter provides a detailed overview of some of the primary spectroscopic methods that
have contributed to the current understanding of molecular nanomagnets (MNs). These …
have contributed to the current understanding of molecular nanomagnets (MNs). These …
Understanding Thermodynamic and Spectroscopic Properties of Tetragonal Mn12 Single-Molecule Magnets from Combined Density Functional Theory/Spin …
S Ghassemi Tabrizi, AV Arbuznikov… - The Journal of Physical …, 2016 - ACS Publications
We apply broken-symmetry density functional theory to determine isotropic exchange-
coupling constants and local zero-field splitting (ZFS) tensors for the tetragonal Mn12 t BuAc …
coupling constants and local zero-field splitting (ZFS) tensors for the tetragonal Mn12 t BuAc …
Experimental and Theoretical Studies on the Magnetic Anisotropy in Lanthanide(III)‐Centered Fe3Ln Propellers
Abstract Compounds [Fe3Ln (tea) 2 (dpm) 6](Fe3Ln; Ln= Tb–Yb, H3tea= triethanolamine,
Hdpm= dipivaloylmethane) were synthesized as lanthanide (III)‐centered variants of …
Hdpm= dipivaloylmethane) were synthesized as lanthanide (III)‐centered variants of …