Replacing planar aromatic rings in drug molecules with C (sp 3)-rich isosteric mimetics, such
as bicyclo [n. 1.1] alkanes, can significantly alter their physicochemical and pharmacokinetic …

This research explores the enantioselective hydrosulfonylation of various α, β‐unsaturated
carbonyl compounds via the use of visible light and redox‐active chiral Ni‐catalysis …

Abstract Efficient methods for synthesizing 1, 2‐aryl (alkenyl) heteroatomic cores,
encompassing heteroatoms such as nitrogen, oxygen, sulfur, and halogens, are of …

Abstract (Hetero) arene reduction is one of the key avenues for synthesizing related cyclic
alkenes and alkanes. While catalytic hydrogenation and Birch reduction are the two broadly …

The carboamination of unsaturated molecules using bifunctional reagents is considered an
attractive approach for the synthesis of nitrogen-containing compounds. However …

The past century has witnessed a large number of reports on the Z/E isomerization of
alkenes. However, the vast majority of them are still limited to the isomerization of di-and tri …

Sigma bond cleavage through electronically excited states allows synthetically useful
transformations with two radical species. Direct excitation of simple aryl halides to form both …

Nitrogen‐centered radicals (NCRs) have been widely recognized as versatile synthetic
intermediates for the construction of nitrogen containing molecules of high value. As such …

Visible-light photocatalysis has evolved as a powerful technique to enable controllable
radical reactions. Exploring unique photocatalytic mode for obtaining new chemoselectivity …

As a type of elementary organic compounds containing N− N single bond, hydrazone
involved chemical conversions are extremely extensive, but they are mainly limited to N2 …