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Octahedral Bipyridine and Bipyrimidine Dioxomolybdenum(VI) Complexes: Characterization, Application in Catalytic Epoxidation, and Density Functional Mechanistic …
FE Kühn, M Groarke, É Bencze… - … A European Journal, 2002 - Wiley Online Library
Complexes of the general formula [MoO2X2L2](X= Cl, Br, Me; L2= bipy, bpym) have been
prepared and fully characterized, including X‐ray crystallographic investigations of all six …
prepared and fully characterized, including X‐ray crystallographic investigations of all six …
Organometallic compounds for epoxidation chemistry: A brief insight into research developments
FE Kühn - Journal of Organometallic Chemistry, 2023 - Elsevier
Catalytic epoxidation reactions are an important area in chemical industries. Since the
1960s high oxidation state transition metal complexes have been examined and applied as …
1960s high oxidation state transition metal complexes have been examined and applied as …
[HTML][HTML] Molybdenum (VI) complexes with ligands derived from 5-(2-pyridyl)-2H-tetrazole as catalysts for the epoxidation of olefins
The development of effective catalytic epoxidation processes that are an alternative to
stoichiometric non-selective oxidation routes is important to meet environmental …
stoichiometric non-selective oxidation routes is important to meet environmental …
Lewis base adducts of bis-(halogeno) dioxomolybdenum (VI): syntheses, structures, and catalytic applications
FE Kühn, AD Lopes, AM Santos, E Herdtweck… - Journal of Molecular …, 2000 - Elsevier
Reaction of solvent substituted MoO2X2 (Solv) 2 complexes ((Solv)= THF, CH3CN) with
mono-and bidentate nitrogen and oxygen donor ligands leads to complexes of the type …
mono-and bidentate nitrogen and oxygen donor ligands leads to complexes of the type …
Synthesis and Catalytic Epoxidation Activity with TBHP and H2O2 of Dioxo-, Oxoperoxo-, and Oxodiperoxo Molybdenum(VI) and Tungsten(VI) Compounds Containing Monodentate or Bidentate Phosphine Oxide Ligands: Crystal Structures of WCl2(O)2(OPMePh2)2, WCl2(O)(O2)(OPMePh2)2, MoCl2(O)2 …
A Jimtaisong, RL Luck - Inorganic chemistry, 2006 - ACS Publications
The dioxo tungsten (VI) and molybdenum (VI) complexes WCl2 (O) 2 (OPMePh2) 2, WCl2
(O) 2dppmO2, and MoCl2 (O) 2dppmO2, the oxoperoxo compounds WCl2 …
(O) 2dppmO2, and MoCl2 (O) 2dppmO2, the oxoperoxo compounds WCl2 …
Synergistic hollow CoMo oxide dual catalysis for tandem oxygen transfer: Preferred aerobic epoxidation of cyclohexene to 1, 2-epoxycyclohexane
W Zhong, M Liu, J Dai, J Yang, L Mao, D Yin - Applied Catalysis B …, 2018 - Elsevier
The CoMo hollow bimetallic oxide has been exploited in the aerobic epoxidation of
cyclohexene containing labile allylic hydrogen atoms using ethylbenzene as a solvent …
cyclohexene containing labile allylic hydrogen atoms using ethylbenzene as a solvent …
(Dimethyl) dioxomolybdenum (VI) complexes: syntheses and catalytic applications
FE Kühn, AM Santos, AD Lopes, IS Gonçalves… - Journal of Molecular …, 2000 - Elsevier
Reaction of MoO2Br2S2 complexes [S= THF, CH3CN] with bidentate nitrogen donor ligands
(L2) leads to complexes of the type MoO2Br2L2 in good yields, L2= substituted …
(L2) leads to complexes of the type MoO2Br2L2 in good yields, L2= substituted …
Molybdenum η3-Allyl Dicarbonyl Complexes as a New Class of Precursors for Highly Reactive Epoxidation Catalysts with tert-Butyl Hydroperoxide
JC Alonso, P Neves, MJ Pires da Silva, S Quintal… - …, 2007 - ACS Publications
New Mo (II) diimine derivatives of [Mo (η3-allyl) X (CO) 2 (CH3CN) 2](allyl= C3H5 and
C5H5O; X= Cl, Br) were prepared, and [Mo (η3-C3H5) Cl (CO) 2 (BIAN)](BIAN= 1, 4-(4 …
C5H5O; X= Cl, Br) were prepared, and [Mo (η3-C3H5) Cl (CO) 2 (BIAN)](BIAN= 1, 4-(4 …
A MoVI grafted Metal Organic Framework: Synthesis, characterization and catalytic investigations
We present the post-modification of a gallium based Metal Organic Framework, COMOC-4,
with a Mo-complex. The resulting Mo@ COMOC-4 was characterized by means of N 2 …
with a Mo-complex. The resulting Mo@ COMOC-4 was characterized by means of N 2 …
Organorhenium (VII) and organomolybdenum (VI) oxides: synthesis and application in oxidation catalysis
FE Kühn, AM Santos, IS Gonçalves… - Applied …, 2001 - Wiley Online Library
Methyltrioxorhenium (VII) has found numerous applications in various catalytic processes. In
olefin epoxidation its activity can be enhanced by the addition of aromatic Lewis base …
olefin epoxidation its activity can be enhanced by the addition of aromatic Lewis base …