In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Conspectus Recently, alkene dicarbofunctionalization, ie, the powerful organic synthesis
method of alkene difunctionalization with two carbon sources, emerged as a formidable …

The development of transition metal (TM) catalysis for organic synthesis under visible light
without recourse to typical photoredox catalysts has become a rapidly growing area of …

We report the first palladium hydride enabled hydroalkenylation of strained molecules. This
new mild protocol proceeds via a regio-and chemoselective hydropalladation step, followed …

An unprecedented asymmetric acyl-carbamoylation of pendant alkenes tethered on aryl
carbamic chlorides with both aliphatic and aromatic aldehydes has been developed via the …

Develo** efficient and selective strategies to approach complex architectures containing
(multi) stereogenic centers has been a long-standing synthetic challenge in both academia …

A Pd (0)/blue light catalyzed carboiodination reaction is reported. A simple, air-stable
catalytic system, utilizing [Pd (allyl) Cl] 2 and DPEPhos, generated a variety of iodinated …

A photoinduced palladium-catalyzed 1, 2-carbofunctionalization of conjugated dienes has
been developed. This mild modular approach, which does not require employment of …

Unveiling the alkyl/Pd hybrid species is a unique sp3-C-centered radical for facilitating
intermolecular hydrogen atom transfer (HAT) in the development of direct alkylation of …

Visible light‐induced Pd catalysis has emerged as a promising subfield of photocatalysis.
The hybrid nature of Pd radical species has enabled a wide array of radical‐based …