Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Gold redox chemistry holds the promise of unique reactivities and selectivities that are
different to other transition metals. Recent studies have utilized strain release, ligand design …

The first example of ancillary (P, N)-ligand-enabled gold-catalyzed C–N cross-coupling
reactions of aryl iodides with amines is reported. The high generality of the reaction in de …

Cycling between Au (I) and Au (III) is challenging, so gold-catalyzed cross-couplings are
rare. The (MeDalphos) AuCl complex, which we showed was prone to undergo oxidative …

The reaction of gold reagents [HAuCl4• 3H2O],[AuCl (tht)], or cyclometalated gold (III)
precursor,[C^ NAuCl2] with chiral ((R, R)-(-)-2, 3-bis (t-butylmethylphosphino) quinoxaline) …

Expanding the chemical diversity of metal complexes provides a robust platform to generate
functional bioactive reagents. To access an excellent repository of metal-based compounds …

Metabolic reprogramming is a key cancer hallmark that has led to the therapeutic targeting
of glycolysis. However, agents that target dysfunctional mitochondrial respiration for targeted …

Transition-metal-based approaches to selectively modify proteins hold promise in
addressing challenges in chemical biology. Unique bioorthogonal chemistry can be …

Diamine ligands are effective structural scaffolds for tuning the reactivity of transition-metal
complexes for catalytic, materials, and phosphorescent applications and have been …

A review paper on Au (III) cyclometallated compounds with 2-arylpyridines (2-
phenylpyridine, 2-benzylpyridine, 2-benzoylpyridine, 2-phenoxypyridine, 2 …