Magnetic cooling: a molecular perspective

P Konieczny, W Sas, D Czernia, A Pacanowska… - Dalton …, 2022 - pubs.rsc.org
The magnetocaloriceffect is considered as an energy-efficient and environmentally friendly
technique which can take cooling technology to the next level. Apart from its commercial …

Magnetocaloric and barocaloric effects of metal complexes for solid state cooling: Review, trends and perspectives

MS Reis - Coordination Chemistry Reviews, 2020 - Elsevier
Solid state refrigeration is a viable alternative for the conventional gas-compression
technology due to the environmental friendliness of its materials, energy efficiency, and low …

Self-Assembly Bifunctional Tetranuclear Ln2Ni2 Clusters: Magnetic Behaviors and Highly Efficient Conversion of CO2 under Mild Conditions

N Qiao, XY **n, XF Guan, CX Zhang… - Inorganic …, 2022 - ACS Publications
A series of heterometallic tetranuclear clusters, Ln2Ni2 (NO3) 4L4 (μ3-OCH3) 2· 2
(CH3CN)(Ln= Gd (1), Tb (2), Dy (3), Ho (4), Er (5); HL= methyl 3-methoxysalicylate), were …

Wheel-like Ln18 Cluster Organic Frameworks for Magnetic Refrigeration and Conversion of CO2

TQ Song, J Dong, AF Yang, XJ Che, HL Gao… - Inorganic …, 2018 - ACS Publications
Two isostructural 2D MOFs ([Ln7 (CDA) 6 (HCOO) 3 (μ3-OH) 6 (H2O) 8] n, abbreviated as 1-
Gd and 2-Dy) were successfully synthesized under solvothermal conditions. The self …

Formation of nanocluster {Dy12} containing Dy-exclusive vertex-sharing [Dy 4 (μ 3-OH) 4] cubanes via simultaneous multitemplate guided and step-by-step assembly

XF Ma, HL Wang, ZH Zhu, B Li, KQ Mo, HH Zou… - Dalton …, 2019 - pubs.rsc.org
The formation of high-nuclearity clusters of lanthanide usually involves many complicated
self-assembly processes. Thus, tracking the formation process is extremely difficult and …

Magnetocaloric effect in 1D-polymers bearing 15-metallacrown-5 {GdCu 5} 3+ units and anionic oxalate complexes

AV Pavlishchuk, SV Kolotilov, M Zeller… - Dalton …, 2024 - pubs.rsc.org
Two complexes {[GdCu5 (GlyHA) 5 (H2O) 7Cr (C2O4) 3]· 11.02 H2O} n (1) and {{[GdCu5
(GlyHA) 5 (H2O) 6] μ2-[Cu (C2O4) 2 (H2O)]} 2μ4-[Cu (C2O4) 2]· 15.8 H2O} n (2), were …

Heterometallic Heptanuclear [Cu5Ln2] (Ln = Tb, Dy, and Ho) Single-Molecule Magnets Organized in One-Dimensional Coordination Polymeric Network

A Dey, S Das, S Kundu, A Mondal… - Inorganic …, 2017 - ACS Publications
The reaction of a multisite coordination ligand, LH3, with Cu (II) salts and Ln (NO3) 3· n H2O
in a 1: 2: 1 stoichiometric ratio in the presence of triethylamine was found to afford a series of …

Filling the Missing Links of M3n Prototype 3d-4f and 4f Cyclic Coordination Cages: Syntheses, Structures, and Magnetic Properties of the Ni10Ln5 and the Er3n …

GJ Zhou, WP Chen, Y Yu, L Qin, T Han… - Inorganic …, 2017 - ACS Publications
In this paper, we proposed a number rule for 3d-4f and 4f cyclic coordination cages (CCCs);
that is, CCCs consisting of vertex-sharing M4 (μ3-OH) 4 (M= 3d transition metal or 4f …

Aggregation of [Ln III12] clusters by the dianion of 3-formylsalicylic acid. Synthesis, crystal structures, magnetic and luminescence properties

AS Dinca, A Mindru, D Dragancea, C Tiseanu… - Dalton …, 2019 - pubs.rsc.org
Three isostrucutral dodecanuclear clusters with the general formula [Ln12 (fsa) 12 (μf3-OH)
12 (DMF) 12]· nDMF (fsa2− is the dianion of 3-formylsalicylic acid; Ln= Eu 1, Gd 2, Dy 3) …

One-dimensional coordination polymers of whole row rare earth tris-pivalates

D Tsymbarenko, I Martynova, D Grebenyuk… - Journal of Solid State …, 2018 - Elsevier
Fourteen 1D coordination polymers of rare earth pivalates [Ln (Piv) 3]∞(Ln= Y, La, Pr, Nd,
Sm− Lu) were synthesized and characterized by powder X-ray diffraction, IR spectroscopy …