Iridium-catalyzed selective isomerization of primary allylic alcohols
H Li, C Mazet - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus This Account presents the development of the iridium-catalyzed isomerization of
primary allylic alcohols in our laboratory over the past 8 years. Our initial interest was driven …
primary allylic alcohols in our laboratory over the past 8 years. Our initial interest was driven …
A Decade of Advancements in Pauson–Khand‐Type Reactions
HW Lee, FY Kwong - European Journal of Organic Chemistry, 2010 - Wiley Online Library
This Microreview illustrates the conceptual evolution ofPauson–Khand‐type reactions and
the recent advancements in catalyst design and applications. Intra‐and intermolecular …
the recent advancements in catalyst design and applications. Intra‐and intermolecular …
Iron-catalyzed tunable and site-selective olefin transposition
The catalytic isomerization of C–C double bonds is an indispensable chemical
transformation used to deliver higher-value analogues and has important utility in the …
transformation used to deliver higher-value analogues and has important utility in the …
Platinum metals in the catalytic asymmetric isomerization of allylic alcohols
L Mantilli, C Mazet - Chemistry letters, 2011 - academic.oup.com
Past and recent advances in the metal-catalyzed asymmetric isomerization of allylic alcohols
into carbonyl compounds are discussed in the present Highlight. Emphasis is placed on …
into carbonyl compounds are discussed in the present Highlight. Emphasis is placed on …
Stereoselective tandem iridium-catalyzed alkene isomerization-cope rearrangement of ω-diene epoxides: Efficient access to acyclic 1, 6-dicarbonyl compounds
The Cope rearrangement of 2, 3-divinyloxiranes, a rare example of epoxide C–C bond
cleavage, results in 4, 5-dihydrooxepines which are amenable to hydrolysis, furnishing 1, 6 …
cleavage, results in 4, 5-dihydrooxepines which are amenable to hydrolysis, furnishing 1, 6 …
Total Synthesis of (−)‐Nakadomarin A
A highly efficient 12‐step synthesis of the marine alkaloid (−)‐nakadomarin A has been
accomplished. The key advanced intermediate, a tetracyclic ketone derivative, was …
accomplished. The key advanced intermediate, a tetracyclic ketone derivative, was …
Improved catalysts for the iridium‐catalyzed asymmetric isomerization of primary allylic alcohols based on Charton analysis
L Mantilli, D Gérard, S Torche… - … –A European Journal, 2010 - Wiley Online Library
An improved generation of chiral cationic iridium catalysts for the asymmetric isomerization
of primary allylic alcohols is disclosed. The design of these air‐stable complexes relied on …
of primary allylic alcohols is disclosed. The design of these air‐stable complexes relied on …
Iridium-catalyzed isomerization of primary allylic alcohols under mild reaction conditions
L Mantilli, C Mazet - Tetrahedron Letters, 2009 - Elsevier
The isomerization of primary allylic alcohols into the corresponding aldehydes has been
accomplished using an analogue of Crabtree's iridium hydrogenation catalyst and by …
accomplished using an analogue of Crabtree's iridium hydrogenation catalyst and by …
Stereoselective Access to Fully Substituted Aldehyde‐Derived Silyl Enol Ethers by Iridium‐Catalyzed Alkene Isomerization
An in situ generated cationic Ir‐catalyst isomerizes simple allylic silyl ethers into valuable,
fully substituted aldehyde‐derived silyl enol ethers. Importantly, by judicious choice of …
fully substituted aldehyde‐derived silyl enol ethers. Importantly, by judicious choice of …
Nickel-Catalyzed Reductive Cycloisomerization of Enynes with CO2
Carboxylate groups are ubiquitous in bioactive molecules. The syntheses of carboxylates
from petroleum feedstock require a series of oxidation reactions. CO2 represents a cheap …
from petroleum feedstock require a series of oxidation reactions. CO2 represents a cheap …