Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Multiscale CO2 Electrocatalysis to C2+ Products: Reaction Mechanisms, Catalyst Design, and Device Fabrication

T Yan, X Chen, L Kumari, J Lin, M Li, Q Fan… - Chemical …, 2023 - ACS Publications
Electrosynthesis of value-added chemicals, directly from CO2, could foster achievement of
carbon neutral through an alternative electrical approach to the energy-intensive …

High carbon utilization in CO2 reduction to multi-carbon products in acidic media

Y **e, P Ou, X Wang, Z Xu, YC Li, Z Wang, JE Huang… - Nature Catalysis, 2022 - nature.com
Renewable electricity-powered CO2 reduction to multi-carbon (C2+) products offers a
promising route to realization of low-carbon-footprint fuels and chemicals. However, a major …

Engineering Single-Atom Active Sites on Covalent Organic Frameworks for Boosting CO2 Photoreduction

L Ran, Z Li, B Ran, J Cao, Y Zhao, T Shao… - Journal of the …, 2022 - ACS Publications
Solar carbon dioxide (CO2) conversion is an emerging solution to meet the challenges of
sustainable energy systems and environmental/climate concerns. However, the construction …

Adjacent Copper Single Atoms Promote C–C Coupling in Electrochemical CO2 Reduction for the Efficient Conversion of Ethanol

W **a, Y **e, S Jia, S Han, R Qi, T Chen… - Journal of the …, 2023 - ACS Publications
The electrochemical CO2 reduction reaction (CO2RR) using renewable electricity is one of
the most promising strategies for reaching the goal of carbon neutrality. Multicarbonous …

Coverage-driven selectivity switch from ethylene to acetate in high-rate CO2/CO electrolysis

P Wei, D Gao, T Liu, H Li, J Sang, C Wang… - Nature …, 2023 - nature.com
Tuning catalyst microenvironments by electrolytes and organic modifications is effective in
improving CO2 electrolysis performance. An alternative way is to use mixed CO/CO2 feeds …

Boosting electrocatalytic CO2–to–ethanol production via asymmetric C–C coupling

P Wang, H Yang, C Tang, Y Wu, Y Zheng… - Nature …, 2022 - nature.com
Electroreduction of carbon dioxide (CO2) into multicarbon products provides possibility of
large-scale chemicals production and is therefore of significant research and commercial …

Gas diffusion electrodes, reactor designs and key metrics of low-temperature CO2 electrolysers

D Wakerley, S Lamaison, J Wicks, A Clemens… - Nature Energy, 2022 - nature.com
CO2 emissions can be recycled via low-temperature CO2 electrolysis to generate products
such as carbon monoxide, ethanol, ethylene, acetic acid, formic acid and propanol. In recent …

Conversion of CO2 to multicarbon products in strong acid by controlling the catalyst microenvironment

Y Zhao, L Hao, A Ozden, S Liu, RK Miao, P Ou… - Nature …, 2023 - nature.com
Electrosynthesis of multicarbon products from the reduction of CO2 in acidic electrolytes is a
promising approach to overcoming CO2 reactant loss in alkaline and neutral electrolytes; …

Modulating adsorbed hydrogen drives electrochemical CO2-to-C2 products

J Feng, L Zhang, S Liu, L Xu, X Ma, X Tan, L Wu… - Nature …, 2023 - nature.com
Electrocatalytic CO2 reduction is a typical reaction involving two reactants (CO2 and H2O).
However, the role of H2O dissociation, which provides active* H species to multiple …