The copolymerization of CO2 and epoxides presents a transformative approach to
converting greenhouse gases into aliphatic polycarbonates (CO2-PCs), thereby reducing …

Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy
for manipulating polymer properties. Controlled synthetic routes to prepare degradable …

Understanding the chemistry underpinning intermetallic synergy and the discovery of
generally applicable structure-performances relationships are major challenges in catalysis …

Carbon dioxide (CO2) is considered a renewable one-carbon building block for chemical
synthesis owing to its abundance, low toxicity, nonflammability, and availability. The …

Within the broader area of heterobimetallic catalysis, Al/M compounds (M= any metal) are
promising for the design and execution of catalytic manifolds. This Perspective reviews …

Carbon dioxide copolymerization is a front‐runner CO2 utilization strategy but its viability
depends on improving the catalysis. So far, catalyst structure‐performance correlations have …

Dinuclear polymerization catalysts can show high activity and control. Understanding how to
design for synergy between the metals is important to improving catalytic performances …

Polyesters carrying polar main-chain ester linkages exhibit distinct material properties for
diverse applications and thus play an important role in today's plastics economy. It is …

Since 2016, when simple triethylborane (Et3B) was revealed as a very capable catalyst for
the copolymerization of epoxides and carbon dioxide, research effort regarding this type of …

Foldamer catalysis has been developed prosperously in various fields due to its enzyme-
mimic feature with admirable activity and selectivity, while there is still a blank for its …