Hessian geometry of nonequilibrium chemical reaction networks and entropy production decompositions

TJ Kobayashi, D Loutchko, A Kamimura… - Physical Review …, 2022 - APS
We derive the Hessian geometric structure of nonequilibrium chemical reaction networks on
the flux and force spaces induced by the Legendre duality of convex dissipation functions …

On the role of geometry in statistical mechanics and thermodynamics. I. Geometric perspective

O Esen, M Grmela, M Pavelka - Journal of Mathematical Physics, 2022 - pubs.aip.org
This paper contains a fully geometric formulation of the General Equation for Non-
Equilibrium Reversible-Irreversible Coupling (GENERIC). Although GENERIC, which is the …

Information geometry of dynamics on graphs and hypergraphs

TJ Kobayashi, D Loutchko, A Kamimura… - Information …, 2024 - Springer
We introduce a new information-geometric structure associated with the dynamics on
discrete objects such as graphs and hypergraphs. The presented setup consists of two …

Variational structures beyond gradient flows: a macroscopic fluctuation-theory perspective

RIA Patterson, DRM Renger, U Sharma - Journal of Statistical Physics, 2024 - Springer
Macroscopic equations arising out of stochastic particle systems in detailed balance (called
dissipative systems or gradient flows) have a natural variational structure, which can be …

The Geometry of Thermodynamic Uncertainty Relations in Chemical Reaction Networks

D Loutchko, Y Sughiyama, TJ Kobayashi - arxiv preprint arxiv:2308.04806, 2023 - arxiv.org
Recently, Hessian geometry-an extension of information geometry-has emerged as a
framework to naturally connect the geometries appearing in the theory of chemical reaction …

EDP-convergence for a linear reaction-diffusion system with fast reversible reaction

A Stephan - Calculus of Variations and Partial Differential …, 2021 - Springer
We perform a fast-reaction limit for a linear reaction-diffusion system consisting of two
diffusion equations coupled by a linear reaction. We understand the linear reaction-diffusion …

Orthogonality of fluxes in general nonlinear reaction networks

J Zimmer, DR Renger - arxiv preprint arxiv:1912.06436, 2019 - arxiv.org
We consider the chemical reaction networks and study currents in these systems. Reviewing
recent decomposition of rate functionals from large deviation theory for Markov processes …

Macroscopic Fluctuation Theory versus large-deviation-induced GENERIC

DR Renger - arxiv preprint arxiv:2402.04092, 2024 - arxiv.org
Recent developments in Macroscopic Fluctuation Theory show that many interacting particle
systems behave macroscopically as a combination of a gradient flow with Hamiltonian …

Geometry of nonequilibrium chemical reaction networks and generalized entropy production decompositions

TJ Kobayashi, D Loutchko, A Kamimura… - arxiv preprint arxiv …, 2022 - arxiv.org
We derive the Hessian geometric structure of nonequilibrium chemical reaction networks
(CRN) on the flux and force spaces induced by the Legendre duality of convex dissipation …

On geometry of multiscale mass action law and its fluctuations

A Ajji, J Chaouki, O Esen, M Grmela, V Klika… - Physica D: Nonlinear …, 2023 - Elsevier
The classical mass action law in chemical kinetics is put into the context of geometric
multiscale thermodynamics, which allows for description of chemical reactions with inertial …