[HTML][HTML] The known-unknowns of anomalous underscreening in concentrated electrolytes

GR Elliott, KP Gregory, H Robertson, VSJ Craig… - Chemical Physics …, 2024 - Elsevier
Electrolytes are central to life and technology but lack complete understanding. Recent
experiments with highly concentrated electrolytes have revealed electrostatic decay lengths …

Phase transitions and electrochemical properties of ionic liquids and ionic liquid—Solvent mixtures

C Cruz, A Ciach - Molecules, 2021 - mdpi.com
Recent advances in studies of ionic liquids (IL) and ionic liquid–solvent mixtures are
reviewed. Selected experimental, simulation, and theoretical results for electrochemical …

A screening of results on the decay length in concentrated electrolytes

H Jäger, A Schlaich, J Yang, C Lian, S Kondrat… - Faraday …, 2023 - pubs.rsc.org
Screening of electrostatic interactions in room-temperature ionic liquids and concentrated
electrolytes has recently attracted much attention as surface force balance experiments have …

Structure and Screening in Confined Electrolytes: The Role of Ion Association

S Wang, H Tao, J Yang, J Cheng, H Liu… - The Journal of Physical …, 2024 - ACS Publications
The effect of ionic association on the structure and property of confined electrolytes is
investigated using the classical density functional theory. We find that ionic association …

Scaling perspectives of underscreening in concentrated electrolyte solutions

SA Safran, PA Pincus - Soft Matter, 2023 - pubs.rsc.org
We present a scaling view of underscreening observed in salt solutions in the range of
concentrations greater than about 1 M, in which the screening length increases with …

Anomalous underscreening in the restricted primitive model

A Härtel, M Bültmann, F Coupette - Physical Review Letters, 2023 - APS
Underscreening is a collective term for charge correlations in electrolytes decaying slower
than the Debye length. Anomalous underscreening refers to phenomenology that cannot be …

Ionic screening in bulk and under confinement

J Zeman, S Kondrat, C Holm - The Journal of Chemical Physics, 2021 - pubs.aip.org
Recent experiments have shown that the repulsive force between atomically flat, like-
charged surfaces confining room-temperature ionic liquids or concentrated electrolytes …

Solvent Effects on Structure and Screening in Confined Electrolytes

J Yang, S Kondrat, C Lian, H Liu, A Schlaich, C Holm - Physical Review Letters, 2023 - APS
Using classical density functional theory, we investigate the influence of solvent on the
structure and ionic screening of electrolytes under slit confinement and in contact with a …

Underscreening in concentrated electrolytes: re-entrant swelling in polyelectrolyte brushes

H Robertson, GR Elliott, ARJ Nelson… - Physical Chemistry …, 2023 - pubs.rsc.org
Hypersaline environments are ubiquitous in nature and are found in myriad technological
processes. Recent empirical studies have revealed a significant discrepancy between …

Direct measurement of surface forces: recent advances and insights

W Lin, J Klein - Applied Physics Reviews, 2021 - pubs.aip.org
The direct measurement of forces between atomically smooth mica surfaces down to sub-
nanometer separation was pioneered over 50 years ago and has yielded deep …