Electrochemical synthesis of nanostructured ordered intermetallic materials under ambient conditions
T Gong, KK Rudman, B Guo… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus The enhanced catalytic properties of alloy nanostructures have made them a
focus of extensive research in the field of catalysis. Alloy nanostructures can be classified …
focus of extensive research in the field of catalysis. Alloy nanostructures can be classified …
A MOF-supported Pd1–Au1 dimer catalyses the semihydrogenation reaction of acetylene in ethylene with a nearly barrierless activation energy
The removal of acetylene from ethylene streams is key in industry for manufacturing
polyethylene. Here we show that a well-defined Pd1–Au1 dimer, anchored to the walls of a …
polyethylene. Here we show that a well-defined Pd1–Au1 dimer, anchored to the walls of a …
Structure evolution and specific effect for catalysis of atomically ordered intermetallic compounds
Atomically ordered intermetallic compounds (IMCs) have been extensively studied for
exploring catalysts with high activity, selectivity, and longevity. Compared to the random …
exploring catalysts with high activity, selectivity, and longevity. Compared to the random …
Bimetallic clusters confined inside silicalite-1 for stable propane dehydrogenation
The noble metal-based bimetallic clusters with high atom utilization and surface energy
have been widely applied in heterogeneous catalysis, but the stabilization of these …
have been widely applied in heterogeneous catalysis, but the stabilization of these …
Experimental study and modeling of the liquid phase hydrogenation of acetylene
Selective hydrogenation of acetylene is an important process for both ethylene purification
and ethylene production from acetylene in the industry. Herein, we proposed liquid phase …
and ethylene production from acetylene in the industry. Herein, we proposed liquid phase …
Atomic intimacy in Pd1Ni/SiO2 single-atom alloy prepared by galvanic replacement for enhanced semi-hydrogenation of acetylene
S Liu, D Wu, F Yang, K Chen, Z Luo, J Li… - Chemical Engineering …, 2024 - Elsevier
Metal single-atom alloys (SAAs) are important catalysts in many catalytic reactions, while the
preparation of metal SAA catalysts is a major challenge because the metal species can …
preparation of metal SAA catalysts is a major challenge because the metal species can …
IrGa bimetallic catalyst with atomical metal dispersion for propane dehydrogenation with high stability
Industrial catalysts for alkane dehydrogenation to olefins suffer from fast deactivation due to
the coking and sintering of active metal under harsh reaction conditions. Herein, iridium, a …
the coking and sintering of active metal under harsh reaction conditions. Herein, iridium, a …
Highly Active and Stable Isolated Irδ+ Sites in Iridium Phosphide for Propane Dehydrogenation
Develo** highly stable catalysts at high temperatures while maintaining high activity and
selectivity has been a focus of research for propane dehydrogenation (PDH). Herein, we …
selectivity has been a focus of research for propane dehydrogenation (PDH). Herein, we …
Thermally induced intermetallic Rh 1 Zn 1 nanoparticles with high phase-purity for highly selective hydrogenation of acetylene
Ordered M1Zn1 intermetallic phases with structurally isolated atom sites offer unique
electronic and geometric structures for catalytic applications, but lack reliable industrial …
electronic and geometric structures for catalytic applications, but lack reliable industrial …
Acetylene Semihydrogenation over Pd–Bi Intermetallic Compounds: A DFT Combined with Microkinetic Modeling Study
BB Li, HY Ma, GC Wang - Langmuir, 2024 - ACS Publications
Acetylene semihydrogenation is an important process both theoretically and experimentally.
Pure Pd catalysts usually suffer from limited selectivity for ethylene products and poor …
Pure Pd catalysts usually suffer from limited selectivity for ethylene products and poor …