Hybrid organic− inorganic polyoxometalate compounds: from structural diversity to applications

A Dolbecq, E Dumas, CR Mayer, P Mialane - Chemical reviews, 2010 - ACS Publications
Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded
as soluble oxide fragments. They exhibit a great diversity of sizes, nuclearities, and shapes …

Recent advances in polyoxothiometalate chemistry

A Elliott, HN Miras - Journal of Coordination Chemistry, 2022 - Taylor & Francis
Despite the proliferation of tungstate and molybdate polyoxometalates (POMs) the inclusion
of sulfides into these structures proved to be challenging. The use of appropriate preformed …

Molecular weights of cyclic and hollow clusters measured by DOSY NMR spectroscopy

S Floquet, S Brun, JF Lemonnier, M Henry… - Journal of the …, 2009 - ACS Publications
The Stokes− Einstein expression of the diffusion coefficient as a function of the
hydrodynamic radius of the diffusing object does not explicitly carry the mass dependency of …

Controllable assembly of multicarboxylic acids functionalized heteropolyoxomolybdates and allochroic properties

Y Liang, S Li, D Yang, P Ma, J Niu… - Journal of Materials …, 2015 - pubs.rsc.org
A series of inorganic–organic hybrid heteropolyoxomolybdates built from [TeMo6O21] 2−
polyoxoanions and multicarboxylic acids including (C3N2H5) 4H6 [(TeMo6O21) 2 {O2C …

Tuning the electrocatalytic hydrogen evolution reaction promoted by [Mo 2 O 2 S 2]-based molybdenum cycles in aqueous medium

A Hijazi, JC Kemmegne-Mbouguen, S Floquet… - Dalton …, 2013 - pubs.rsc.org
We report the syntheses and characterizations, in the solid state and in solution, of three
new cyclic polyoxothiomolybdates self-assembled around 2, 5-dimethylterephthalate (DMT) …

Ligand-controlled formation of covalently modified antimoniomolybdates and their photochromic properties

J Wang, Y Liang, P Ma, D Zhang, J Niu, J Wang - CrystEngComm, 2017 - pubs.rsc.org
Four inorganic–organic hybrids based on multicarboxylic acids and antimoniomolybdates,
namely,(NH4) 4 (C3N2H5) 4H4 [(SbMo6O21) 2 {OOC (CH2) 4COO} 3]· 7H2O (1),(NH4) 8 …

Self assembly of carboxylate/alcoholate functionalized ring-shape phosphomolybdates

D Yang, Y Liang, P Ma, S Li, J Wang, J Niu - CrystEngComm, 2014 - pubs.rsc.org
We report a simple and efficient approach to incorporate organic groups into
polymolybdates by reaction of H3PO3 with Na2MoO4· 2H2O/(NH4) 6Mo7O24· 4H2O and …

Construction of a new binding manner in carboxylic acid-functionalized phosphomolybdates

J Wang, W Shi, S Li, Q Mao, P Ma, J Niu, J Wang - Dalton Transactions, 2018 - pubs.rsc.org
Carboxylic acid-functionalized polyoxomolybdates have been widely reported. In this study,
we tried to establish a new connection pattern between an organic carboxylic acid ligand …

Polyoxomolybdates functionalized by a flexible carboxylic acid and their photochromic properties

J Wang, P Ma, Y Wang, D Zhang, J Niu… - Journal of Physics and …, 2017 - Elsevier
Two inorganic-organic hybridized polyoxomolybdates, Cs 8 NaH [(SeMo 6 O 21) C 6 H 3 O
3 (CH 2 CO 2) 3] 2· 10H 2 O (1) and Cs 8 H 4 [(AsMo 6 O 21) C 6 H 3 O 3 (CH 2 CO 2) 3] 2 …

Syntheses, Characterizations and Properties of [Mo2O2S2]-Based Oxothiomolybdenum Rings Incorporating Carboxylate Ligands

QY Xu, Z **n, MJ Hu, HT Shi, AQ Jia… - Journal of Cluster Science, 2023 - Springer
Three cyclic polyoxothiomolybdates [Mo20O20S20 (OH) 20 (PyD) 2] 4−(1)(PyD2−= 3, 5-
pyridinedicarboxylic acid, C7H6O4N2−),[Mo12O12S12 (OH) 12 (H2O) 5 (NapH)] …