Water dynamics in the hydration shells of biomolecules

D Laage, T Elsaesser, JT Hynes - Chemical Reviews, 2017 - ACS Publications
The structure and function of biomolecules are strongly influenced by their hydration shells.
Structural fluctuations and molecular excitations of hydrating water molecules cover a broad …

Vibrational spectroscopy and dynamics of water

F Perakis, L De Marco, A Shalit, F Tang… - Chemical …, 2016 - ACS Publications
We present an overview of recent static and time-resolved vibrational spectroscopic studies
of liquid water from ambient conditions to the supercooled state, as well as of crystalline and …

The bending mode of water: A powerful probe for hydrogen bond structure of aqueous systems

T Seki, KY Chiang, CC Yu, X Yu, M Okuno… - The journal of …, 2020 - ACS Publications
Insights into the microscopic structure and dynamics of the water's hydrogen-bonded
network are crucial to understand the role of water in biology, atmospheric and geochemical …

[HTML][HTML] Synchrotron-based infrared microspectroscopy under high pressure: An introduction

L Kong, G Liu - Matter and Radiation at Extremes, 2021 - pubs.aip.org
Synchrotron sources with high photon flux, small source size, and broad energy range have
revolutionized ultrafine characterization of condensed matter. With the addition of the …

Vibrational spectroscopy as a probe of structure and dynamics in liquid water

HJ Bakker, JL Skinner - Chemical reviews, 2010 - ACS Publications
Water is, of course, a fascinating and important substance. For such a simple molecule, its
condensed phase properties are surprisingly complex. Here we might mention the many …

IR and Raman spectra of liquid water: Theory and interpretation

BM Auer, JL Skinner - The Journal of chemical physics, 2008 - pubs.aip.org
IR and Raman (parallel-and perpendicular-polarized) spectra in the OH stretch region for
liquid water were measured some years ago, but their interpretation is still controversial. In …

Ultrafast dynamics at water interfaces studied by vibrational sum frequency generation spectroscopy

S Nihonyanagi, S Yamaguchi, T Tahara - Chemical Reviews, 2017 - ACS Publications
We present an overview of studies on the ultrafast dynamics of water at aqueous interfaces
carried out by time-resolved vibrational sum frequency generation (VSFG) spectroscopies …

Coherent multidimensional optical spectroscopy of excitons in molecular aggregates; quasiparticle versus supermolecule perspectives

D Abramavicius, B Palmieri, DV Voronine… - Chemical …, 2009 - ACS Publications
Molecular aggregates are abundant in nature; they form spontaneously in concentrated
solutions and on surfaces and can be synthesized by supramolecular chemistry techniques …

Water vibrations have strongly mixed intra-and intermolecular character

K Ramasesha, L De Marco, A Mandal, A Tokmakoff - Nature chemistry, 2013 - nature.com
The ability of liquid water to dissipate energy efficiently through ultrafast vibrational
relaxation plays a key role in the stabilization of reactive intermediates and the outcome of …

Vibrational couplings and energy transfer pathways of water's bending mode

CC Yu, KY Chiang, M Okuno, T Seki, T Ohto… - Nature …, 2020 - nature.com
Coupling between vibrational modes is essential for energy transfer and dissipation in
condensed matter. For water, different OH stretch modes are known to be very strongly …