[HTML][HTML] Universal properties of relaxation and diffusion in complex materials: Originating from fundamental physics with rich applications

KL Ngai - Progress in Materials Science, 2023 - Elsevier
Complex materials are composed of basic units which invariably interact with anharmonic
potentials. It is well known that the dynamics of systems with anharmonic interaction are …

Relaxation behavior of polymer thin films: Effects of free surface, buried interface, and geometrical confinement

B Li, S Zhang, JS Andre, Z Chen - Progress in Polymer Science, 2021 - Elsevier
The glass transition temperature (T g) of polymer thin films, one of the most important
parameters to characterize the relaxation behavior of polymer chains in a thin film, has been …

T g depression and invariant segmental dynamics in polystyrene thin films

VM Boucher, D Cangialosi, H Yin, A Schönhals… - Soft Matter, 2012 - pubs.rsc.org
We investigate the segmental dynamics and glass transition temperature (Tg) of polystyrene
(PS) thin films. The former is investigated by alternating current (AC) calorimetry and …

Mechanical and viscoelastic properties of confined amorphous polymers

BD Vogt - Journal of Polymer Science Part B: Polymer Physics, 2018 - Wiley Online Library
Confinement of polymers to nanoscale dimensions can dramatically impact their physical
properties. Substantial efforts have focused on the glass transition temperature (Tg) of …

Why we need to look beyond the glass transition temperature to characterize the dynamics of thin supported polymer films

W Zhang, JF Douglas, FW Starr - Proceedings of the National Academy of …, 2018 - pnas.org
There is significant variation in the reported magnitude and even the sign of T g shifts in thin
polymer films with nominally the same chemistry, film thickness, and supporting substrate …

Evaluation of structural and functional properties of citrus pectin film enriched with green tea extract

H Wei, MA Pascall - Polymer Engineering & Science, 2023 - Wiley Online Library
The effects of green tea extract (GTE) concentrations (0%, 1%, 2%, 3%, 4%, and 5%) on the
thicknesses, mechanical strengths, storage/loss moduli, glass transition temperatures (T g) …

Glassy dynamics and glass transition in nanometric layers and films: A silver lining on the horizon

F Kremer, M Tress, EU Mapesa - Journal of Non-Crystalline Solids, 2015 - Elsevier
The long lasting highly controversial discussion on glassy dynamics and the glass transition
temperature of polymers in nanometric layers and films seems to be converging based on a …

Ten (or more) years of dynamics in confinement: Perspectives for 2010

GB McKenna - The European Physical Journal Special Topics, 2010 - Springer
Understanding the dynamics of complex liquids in confinement continues to be a major
fundamental issue in the field of soft condensed matter. In particular there was a series of …

Three-in-One: AIEgen End-Labeling of CO2 Polymer for Visible Fiber Thermometer

C Zhuo, X Yu, Y Cheng, S Liu, M Zhu, X Wang - Macromolecules, 2023 - ACS Publications
Visual temperature sensors are of great significance for environmental management and
industrial process control. Herein, we developed a visual sensing approach based on fiber …

Short-Time Dynamics Reveals Tg Suppression in Simulated Polystyrene Thin Films

Y Zhou, ST Milner - Macromolecules, 2017 - ACS Publications
Suppression of the glass transition temperature, T g, in polymer thin films is of great practical
importance and theoretical significance. It is widely believed that such T g suppression …