Figuration of bowl-shaped π-conjugated molecules: properties and functions

M Saito, H Shinokubo, H Sakurai - Materials Chemistry Frontiers, 2018 - pubs.rsc.org
Figuration of bowl-shaped π-conjugated molecules: properties and functions - Materials Chemistry
Frontiers (RSC Publishing) DOI:10.1039/C7QM00593H Royal Society of Chemistry View PDF …

Corannulene: A curved polyarene building block for the construction of functional materials

MC Stuparu - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus This Account describes a body of research in the design and synthesis of
molecular materials prepared from corannulene. Corannulene (C20H10) is a molecular …

Corannulene: a molecular bowl of carbon with multifaceted properties and diverse applications

E Nestoros, MC Stuparu - Chemical Communications, 2018 - pubs.rsc.org
Unlike typical polycyclic aromatic hydrocarbons, such as coronene, which are flat and
planar, corannulene is a molecular bowl of carbon. It can be imagined as the cap region of …

Perfluoroalkylfullerenes

OV Boltalina, AA Popov, IV Kuvychko… - Chemical …, 2015 - ACS Publications
Perfluoroalkylfullerenes | Chemical Reviews ACS ACS Publications C&EN CAS Find my
institution Log In Chemical Reviews ACS Publications. Most Trusted. Most Cited. Most Read …

Transition-metal-catalyzed difluoromethylation, difluoromethylenation, and polydifluoromethylenation reactions

B Chen, DA Vicic - Organometallic Fluorine Chemistry, 2015 - Springer
One way to introduce fluorine into a molecule is through fluoroalkylation reactions.
Transition-metal catalysts play an increasing role in selectively incorporating fluoroalkyl …

Decafluorinated and Perfluorinated Warped Nanographenes: Synthesis, Structural Analysis, and Properties

XP Zhang, SW Ying, YL Zhang, WX Zhang… - Journal of the …, 2024 - ACS Publications
Fluorination is a useful approach for tailoring the physicochemical properties of nanocarbon
materials. However, owing to the violent reactivity of fluorination, achieving edge …

Fulleretic materials: buckyball-and buckybowl-based crystalline frameworks

AM Rice, EA Dolgopolova, NB Shustova - Chemistry of Materials, 2017 - ACS Publications
Merging the intrinsic properties of fullerene (buckyball) and corannulene (buckybowl)
derivatives with the inherent properties of crystalline metal-and covalent-organic frameworks …

Bowl‐Assisted Ball Assembly for Solvent‐Processing the C60 Electron Transport Layer of High‐Performance Inverted Perovskite Solar Cell

Z **ng, F Liu, SH Li, X Huang, A Fan… - Angewandte …, 2023 - Wiley Online Library
Pristine fullerene C60 is an excellent electron transport material for state‐of‐the‐art inverted
structure perovskite solar cells (PSCs), but its low solubility leaves thermal evaporation as …

Synthesis of Pyrrole‐Fused Corannulenes: 1, 3‐Dipolar Cycloaddition of Azomethine Ylides to Corannulene

Y Tokimaru, S Ito, K Nozaki - … Chemie International Edition, 2017 - Wiley Online Library
In the long history of corannulene chemistry, the 1, 3‐dipolar cycloaddition to corannulene is
unprecedented. Reported herein is the 1, 3‐dipolar cycloaddition of a polycyclic aromatic …

Thiophene-fused bowl-shaped polycyclic aromatics with a dibenzo [a, g] corannulene core for organic field-effect transistors

RQ Lu, YN Zhou, XY Yan, K Shi, YQ Zheng… - Chemical …, 2015 - pubs.rsc.org
For the first time, electron-rich thiophene units were fused into the skeleton of corannulene to
extend π-surfaces and tune arrangement in single crystals. Two isomeric butterfly-like …