Corroles at work: A small macrocycle for great applications

C Di Natale, CP Gros, R Paolesse - Chemical Society Reviews, 2022 - pubs.rsc.org
Corrole chemistry has witnessed an impressive boost in studies in the last 20 years, thanks
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …

Milestones and most recent advances in Corrole's Science and Technology

A Mahammed, Z Gross - Journal of the American Chemical …, 2023 - ACS Publications
The renaissance in corrole chemistry is strongly correlated with synthetic breakthroughs that
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …

Hydrogen evolution catalyzed by corrole-chelated nickel complexes, characterized in all catalysis-relevant oxidation states

QC Chen, S Fite, N Fridman, B Tumanskii… - ACS …, 2022 - ACS Publications
Designing catalysts that are not based on precious metals remains a major research priority
worldwide, particularly for the feasible production of hydrogen gas. Given the increasing …

Beneficial Effects on the Cobalt-Catalyzed Hydrogen Evolution Reaction Induced by Corrole Chelation

A Kumar, S Fite, A Raslin, S Kumar, A Mizrahi… - ACS …, 2023 - ACS Publications
Current technologies for the mass production of hydrogen gas, needed for fuel cells, the
synthesis of ammonia, and many other purposes, have an enormous carbon footprint. Less …

[HTML][HTML] Electrocatalytic hydrogen evolution of transition metal (Fe, Co and Cu)–corrole complexes bearing an imidazole group

LW Wu, YF Yao, SY Xu, XY Cao, YW Ren, LP Si… - Catalysts, 2023 - mdpi.com
The study of the hydrogen evolution reaction (HER) by non-noble transition metals is of
great significance for the production of hydrogen energy. In this work, a new 5, 15-bis …

Substituent Effect on Ligand‐Centered Electrocatalytic Hydrogen Evolution of Phosphorus Corroles

G Yang, Z Ullah, W Yang, H Wook Kwon… - …, 2023 - Wiley Online Library
There have been few reports on the substituent effect of main‐group‐element corrole
complexes as ligand‐centered homogeneous electrocatalysts for the hydrogen evolution …

Synthesis, Spectral, Redox, and Sensing Studies of β-Dicyanovinyl-Appended Corroles and Their Metal Complexes

I Yadav, WR Osterloh, KM Kadish… - Inorganic Chemistry, 2023 - ACS Publications
A new family of β-dicyanovinyl (DCV)-appended corroles represented as MTPC (MN)(where
M= 3H, Cu, Ag, and Co (PPh3) and MN= malononitrile and TPC= 5, 10, 15-triphenylcorrole) …

Silver Anniversary of the Renaissance in Metallocorrole Chemistry

A Mahammed, HB Gray, Z Gross - Chemical Reviews, 2025 - ACS Publications
The 1999 discovery of one-pot corrole synthesis opened the floodgates for research on
these unique macrocyclic chelating agents. The enormous impact of this discovery has been …

Molecular geometry and electronic structure of copper corroles

R Bhowmick, S Roy Chowdhury… - Inorganic …, 2023 - ACS Publications
Copper corroles are known for their unique multiconfigurational electronic structures in the
ground state, which arise from the transfer of electrons from the π orbitals of the corrole to …

Corroles: the hitherto elusive parent macrocycle and its metal complexes

A Kumar, P Yadav, M Majdoub… - Angewandte Chemie …, 2021 - Wiley Online Library
Corroles, macrocycles that owe their name to the cobalt‐chelating prosthetic group of
vitamin B12 and share numerous features with the iron‐chelating porphyrin present in heme …