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Corroles at work: A small macrocycle for great applications
C Di Natale, CP Gros, R Paolesse - Chemical Society Reviews, 2022 - pubs.rsc.org
Corrole chemistry has witnessed an impressive boost in studies in the last 20 years, thanks
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …
Milestones and most recent advances in Corrole's Science and Technology
The renaissance in corrole chemistry is strongly correlated with synthetic breakthroughs that
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …
Hydrogen evolution catalyzed by corrole-chelated nickel complexes, characterized in all catalysis-relevant oxidation states
Designing catalysts that are not based on precious metals remains a major research priority
worldwide, particularly for the feasible production of hydrogen gas. Given the increasing …
worldwide, particularly for the feasible production of hydrogen gas. Given the increasing …
Beneficial Effects on the Cobalt-Catalyzed Hydrogen Evolution Reaction Induced by Corrole Chelation
Current technologies for the mass production of hydrogen gas, needed for fuel cells, the
synthesis of ammonia, and many other purposes, have an enormous carbon footprint. Less …
synthesis of ammonia, and many other purposes, have an enormous carbon footprint. Less …
[HTML][HTML] Electrocatalytic hydrogen evolution of transition metal (Fe, Co and Cu)–corrole complexes bearing an imidazole group
LW Wu, YF Yao, SY Xu, XY Cao, YW Ren, LP Si… - Catalysts, 2023 - mdpi.com
The study of the hydrogen evolution reaction (HER) by non-noble transition metals is of
great significance for the production of hydrogen energy. In this work, a new 5, 15-bis …
great significance for the production of hydrogen energy. In this work, a new 5, 15-bis …
Substituent Effect on Ligand‐Centered Electrocatalytic Hydrogen Evolution of Phosphorus Corroles
G Yang, Z Ullah, W Yang, H Wook Kwon… - …, 2023 - Wiley Online Library
There have been few reports on the substituent effect of main‐group‐element corrole
complexes as ligand‐centered homogeneous electrocatalysts for the hydrogen evolution …
complexes as ligand‐centered homogeneous electrocatalysts for the hydrogen evolution …
Synthesis, Spectral, Redox, and Sensing Studies of β-Dicyanovinyl-Appended Corroles and Their Metal Complexes
A new family of β-dicyanovinyl (DCV)-appended corroles represented as MTPC (MN)(where
M= 3H, Cu, Ag, and Co (PPh3) and MN= malononitrile and TPC= 5, 10, 15-triphenylcorrole) …
M= 3H, Cu, Ag, and Co (PPh3) and MN= malononitrile and TPC= 5, 10, 15-triphenylcorrole) …
Silver Anniversary of the Renaissance in Metallocorrole Chemistry
The 1999 discovery of one-pot corrole synthesis opened the floodgates for research on
these unique macrocyclic chelating agents. The enormous impact of this discovery has been …
these unique macrocyclic chelating agents. The enormous impact of this discovery has been …
Molecular geometry and electronic structure of copper corroles
Copper corroles are known for their unique multiconfigurational electronic structures in the
ground state, which arise from the transfer of electrons from the π orbitals of the corrole to …
ground state, which arise from the transfer of electrons from the π orbitals of the corrole to …
Corroles: the hitherto elusive parent macrocycle and its metal complexes
Corroles, macrocycles that owe their name to the cobalt‐chelating prosthetic group of
vitamin B12 and share numerous features with the iron‐chelating porphyrin present in heme …
vitamin B12 and share numerous features with the iron‐chelating porphyrin present in heme …