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Triple-bond vibrations: Emerging applications in energy and biological sciences
Triple bonds, such as that formed between two carbon atoms (ie, C≡ C) or that formed
between one carbon atom and one nitrogen atom (ie, C≡ N), afford unique chemical …
between one carbon atom and one nitrogen atom (ie, C≡ N), afford unique chemical …
Excess spectroscopy and its applications in the study of solution chemistry
Abstract Characterization of structural heterogeneity of liquid solutions and the pursuit of its
nature have been challenging tasks to solution chemists. In the last decade, an emerging …
nature have been challenging tasks to solution chemists. In the last decade, an emerging …
Electro-inductive effect dominates vibrational frequency shifts of conjugated probes on gold electrodes
Interfacial electric fields play a critical role in electrocatalysis and are often characterized by
using vibrational probes attached to an electrode surface. Understanding the physical …
using vibrational probes attached to an electrode surface. Understanding the physical …
Spectroscopic and Computational Study of ZnCl2–Methanol Low-Melting-Temperature Mixtures
Alcoholic electrolyte mixtures have wide applications in industries. In this study, a series of
mixtures composed of ZnCl2 and methanol (MeOH) with ZnCl2 mol% from 6.7 to 25 were …
mixtures composed of ZnCl2 and methanol (MeOH) with ZnCl2 mol% from 6.7 to 25 were …
In situ species analysis of a lithium-ion battery electrolyte containing LiTFSI and propylene carbonate
YQ Wang, H Xu, B Cao, J Ma… - The Journal of Physical …, 2024 - ACS Publications
In this study, we analyzed the species in a model electrolyte consisting of a lithium salt,
lithium bis (trifluoromethane sulfone) imide (LiTFSI), and a widely used neutral solvent …
lithium bis (trifluoromethane sulfone) imide (LiTFSI), and a widely used neutral solvent …
Acidity scales of deep eutectic solvents based on IR and NMR
F Zhou, R Shi, Y Wang, Z Xue, B Zhang… - Physical Chemistry …, 2022 - pubs.rsc.org
Acidic deep eutectic solvents (ADESs) have been utilized in various applications. Clearly, it
is crucial to obtain acidity information that could reveal the relationship with performance …
is crucial to obtain acidity information that could reveal the relationship with performance …
[HTML][HTML] Glycerol as Alternative Co-Solvent for Water Extraction of Polyphenols from Carménère Pomace: Hot Pressurized Liquid Extraction and Computational …
Glycerol is a co-solvent for water extraction that has been shown to be highly effective for
obtaining polyphenol extracts under atmospheric conditions. However, its efficacy under …
obtaining polyphenol extracts under atmospheric conditions. However, its efficacy under …
Influence of Hydration on the Structure and Interactions of Ethaline Deep‐Eutectic Solvent: A Spectroscopic and Computational Study
Deep‐eutectic solvents (DESs) are regarded as alternative green solvents to ionic liquids. In
this work we report the structural properties and hydrogen bonding (H‐bonding) interactions …
this work we report the structural properties and hydrogen bonding (H‐bonding) interactions …
The structural properties of a ZnCl 2–ethylene glycol binary system and the peculiarities at the eutectic composition
ATR-FTIR spectroscopy was performed on a series of ZnCl2–ethylene glycol (EG) mixtures
with a wide-range of compositions (1: 1.5–1: 14 in molar ratios), involving the stable ZnCl2 …
with a wide-range of compositions (1: 1.5–1: 14 in molar ratios), involving the stable ZnCl2 …
Distinguishing between the electrostatic effects and explicit ion interactions in a stark probe
Vibrational Stark probes are incisive tools for measuring local electric fields in a wide range
of chemical environments. The interpretation of the frequency shift often gets complicated …
of chemical environments. The interpretation of the frequency shift often gets complicated …