Force measurements with the atomic force microscope: Technique, interpretation and applications

HJ Butt, B Cappella, M Kappl - Surface science reports, 2005 - Elsevier
The atomic force microscope (AFM) is not only a tool to image the topography of solid
surfaces at high resolution. It can also be used to measure force-versus-distance curves …

Effects of confinement on material behaviour at the nanometre size scale

M Alcoutlabi, GB McKenna - Journal of Physics: Condensed …, 2005 - iopscience.iop.org
In this article, the effects of size and confinement at the nanometre size scale on both the
melting temperature, T m, and the glass transition temperature, T g, are reviewed. Although …

Advances in atomic force microscopy for probing polymer structure and properties

D Wang, TP Russell - Macromolecules, 2018 - ACS Publications
Over the past 30 years, atomic force microscopy (AFM) has played an important role in
elucidating the structure and properties of polymer surfaces. AFM-based techniques have …

Effect of interfacial interactions on the glass transition of polymer thin films

OKC Tsui, TP Russell, CJ Hawker - Macromolecules, 2001 - ACS Publications
Previous studies had demonstrated that the T g of polymer thin films is strongly dependent
on the interactions, γs, between the polymer and the underlying substrate. We present a …

Surface dynamics of glasses

H Tian, Q Xu, H Zhang, RD Priestley, B Zuo - Applied Physics Reviews, 2022 - pubs.aip.org
Two challenging scientific disciplines, ie, the physics of glasses [Anderson, Science 267,
1615 (1995); Kennedy and Norman, Science 309, 75 (2005)] and interface chemistry …

Mechanical characterization of polymers on a nanometer scale through nanoindentation. A study on pile-up and viscoelasticity

D Tranchida, S Piccarolo, J Loos, A Alexeev - Macromolecules, 2007 - ACS Publications
The analysis of nanoindentation force curves collected on polymers through the common
Oliver and Pharr procedure does not lead to a correct evaluation of Young's modulus. In …

Study of elastic modulus and yield strength of polymer thin films using atomic force microscopy

B Du, OKC Tsui, Q Zhang, T He - Langmuir, 2001 - ACS Publications
Nanometer-scale elastic moduli and yield strengths of polycarbonate (PC) and polystyrene
(PS) thin films were measured with atomic force microscopy (AFM) indentation …

Nanoscale mechanical characterization of polymers by AFM nanoindentations: critical approach to the elastic characterization

D Tranchida, S Piccarolo, M Soliman - Macromolecules, 2006 - ACS Publications
AFM nanoindentations show a dependence of penetration, ie, the relative motion between
the sample and the tip (indenter), on material elastic properties when using the same load …

Thickness dependence of the Young's modulus of polymer thin films

J Chang, KB Toga, JD Paulsen, N Menon… - …, 2018 - ACS Publications
The Young's modulus of polymer thin films was measured from bulk films that are
micrometers in thickness down to films having a thickness of∼ 6 nm, which is less than the …

Stretching and Bending Moduli of Bilayer Films Inferred from Wrinkle Patterns

J Chang, N Menon, TP Russell - Macromolecules, 2024 - ACS Publications
Wrinkling patterns were used to investigate the mechanical properties of thin poly
(styrene)(PS)/poly (methyl methacrylate)(PMMA) and PS/gold (Au) bilayer films. Films were …