Unexpected Nucleophilic Substitution Reaction of BODIPY: Preparation of the BODIPY–TEMPO Triad Showing Radical‐Enhanced Intersystem Crossing

K Xu, AA Sukhanov, Y Zhao, J Zhao… - European Journal of …, 2018 - Wiley Online Library
We have discovered a new and unexpected substitution reaction of BODIPY. Through single‐
crystal XRD analysis, DFT calculations, and other complimentary spectroscopic methods, we …

TEMPO-functionalized zinc phthalocyanine: synthesis, magnetic properties, and its utility for electrochemical sensing of ascorbic acid

SE Korkut, D Akyüz, K Özdoğan, Y Yerli, A Koca… - Dalton …, 2016 - pubs.rsc.org
Zinc (II) phthalocyanine (TEMPO-ZnPc), peripherally functionalized with 2, 2, 6, 6-tetramethyl-
1-piperidinyloxy (TEMPO) radicals is synthesized and its magneto structural and …

Magnetic interactions in Spin-labeled Au nanoparticles

V Lloveras, E Badetti, V Chechik… - The Journal of …, 2014 - ACS Publications
A series of gold nanoparticles functionalized with TEMPO-modified disulfide 2 have been
prepared and studied by electron paramagnetic resonance (EPR) spectroscopy, UV–vis …

Facile synthesis and spectral analysis of the bioactive spiroborate compounds as a novel therapeutic agent for computational insights, biological evaluation, and …

M Yildirim, E Yasar, A Necip, M Cimentepe… - Journal of …, 2025 - Elsevier
Boron-containing compounds (BCCs) have emerged as a new class of organic molecules in
pharmaceutical chemistry as novel drug candidates for extensive therapeutic applications. In …

Synthesis, crystal structure, superoxide scavenging activity, anticancer and docking studies of novel adamantyl nitroxide derivatives

X Zhu, J Sun, S Wang, W Bu, M Yao, K Gao… - Journal of Molecular …, 2016 - Elsevier
A novel adamantyl nitroxide derivatives has been synthesized and characterized by IR, ESI-
MS and elemental analysis. Quantum chemical calculations have also been performed to …

Functionalization of sterically hindered catechol and o-benzoquinone with 2,2,6,6-tetramethylpiperidine 1-oxyl

NO Druzhkov, EN Egorova, MV Arsen'ev… - Russian Chemical …, 2016 - Springer
Abstract Sterically hindered 4, 6-di-tert-butyl-3-formylcatechol and 3, 6-di-tert-butyl-o-
benzoquinone react with 4-amino-2, 2, 6, 6-tetramethylpiperidine 1-oxyl to give new chelate …

Heterospin biradicals based on new piperidineoxyl-substituted 3,6-di-tert-butyl-o-benzoquinone

EN Egorova, NO Druzhkov, KA Kozhanov… - Russian Chemical …, 2017 - Springer
A nucleophilic addition reaction of 4-hydroxy-2, 2, 6, 6-tetramethylpiperidine-1-oxyl (OH-
TEMPO) to 3, 6-di-tert-butyl-o-benzoquinone was used to obtain a new sterically hindered o …

[HTML][HTML] X-ray Structures of Precursors of Styrylpyridine-Derivatives Used to Obtain 4-((E)-2-(Pyridin-2-yl)vinyl)benzamido-TEMPO: Synthesis and Characterization

G Soriano-Moro, MJ Percino, AL Sánchez, VM Chapela… - Molecules, 2015 - mdpi.com
The synthesis and characterization of the precursor isomers trans-4-(2-(pyridin-2-yl)
vinylbenzaldehyde (I), trans-4-(2-(pyridin-4-yl) vinylbenzaldehyde (II), trans-4-(2-(pyridin-2 …

Magnetic properties of a new N-TEMPO-tert-butyl substituted salicylaldimines and their biradical palladium (II) complexes

VT Kasumov, Y Yerli, R Topkaya - Solid state sciences, 2013 - Elsevier
A new TEMPO bearing tert-butylated salicylaldimines 1 and 2, as well as early reported 3,
and their bis (N-TEMPO-tert-butylated salicylaldiminato) palladium (II) biradical complexes 4 …

Heterospin Cobalt, Nickel, and Copper Complexes: 4-TEMPO-oxy-3,6-di-tert-butyl-o-Benzoquinone Derivatives

NO Druzhkov, EN Nikolaevskaya… - Russian Journal of …, 2019 - Springer
A series of heterospin bis-o-semiquinone cobalt, nickel, and copper complexes (4-TEMPO-
oxy-3, 6-di-tert-butyl-o-benzoquinone derivatives) is synthesized:(DMSO) Cu (4-TEMPO-O …