Spontaneous resolution, whence and whither: from enantiomorphic solids to chiral liquid crystals, monolayers and macro-and supra-molecular polymers and …
L Pérez-García, DB Amabilino - Chemical Society Reviews, 2007 - pubs.rsc.org
One of the great challenges in stereochemistry is the explanation of why some molecules
resolve spontaneously while others do not. In this critical review the recent advances in the …
resolve spontaneously while others do not. In this critical review the recent advances in the …
Chirality in adsorption on solid surfaces
F Zaera - Chemical Society Reviews, 2017 - pubs.rsc.org
In the present review we survey the main advances made in recent years on the
understanding of chemical chirality at solid surfaces. Chirality is an important topic, made …
understanding of chemical chirality at solid surfaces. Chirality is an important topic, made …
Visible circularly polarized luminescence of octanuclear circular Eu (III) helicate
YB Tan, Y Okayasu, S Katao, Y Nishikawa… - Journal of the …, 2020 - ACS Publications
This work reports on the structural and photophysical characterization of D 4-symmetrical
octanuclear circular LnIII helicates,[(R)-or (S)-iPr-Pybox] 8 (LnIII) 8 (THP) 8 (where Ln= Eu …
octanuclear circular LnIII helicates,[(R)-or (S)-iPr-Pybox] 8 (LnIII) 8 (THP) 8 (where Ln= Eu …
Amplification of chirality in two-dimensional enantiomorphous lattices
The concept of chirality dates back to 1848, when Pasteur manually separated left-handed
from right-handed sodium ammonium tartrate crystals. Crystallization is still an important …
from right-handed sodium ammonium tartrate crystals. Crystallization is still an important …
Crystalline architectures as templates of relevance to the origins of homochirality
I Weissbuch, M Lahav - Chemical Reviews, 2011 - ACS Publications
From the days of Biot1 and Pasteur, 2 when it was recognized that biopolymers are
composed from residues of a single handedness, scientists were puzzled as to the ancestry …
composed from residues of a single handedness, scientists were puzzled as to the ancestry …
Enantiomer surface chemistry: conglomerate versus racemate formation on surfaces
Research on surface chirality is motivated by the need to develop functional chiral surfaces
for enantiospecific applications. While molecular chirality in 3D has been the subject of study …
for enantiospecific applications. While molecular chirality in 3D has been the subject of study …
Effect of molecular chirality on the morphology of biomimetic Langmuir monolayers
N Nandi, D Vollhardt - Chemical reviews, 2003 - ACS Publications
Chirality (originated from the Greek word “cheir”, meaning “hand”) is an expression of
nature, which is observed in its various forms. Traditionally, a lack of symmetry is considered …
nature, which is observed in its various forms. Traditionally, a lack of symmetry is considered …
Stochastic “mirror symmetry breaking” via self-assembly, reactivity and amplification of chirality: relevance to abiotic conditions
I Weissbuch, L Leiserowitz, M Lahav - Prebiotic Chemistry, 2005 - Springer
Theories of prebiotic life suggest that homochirality emerged in Nature in abiotic times via
deterministic or chance scenarios. This chapter deals with experiments demonstrating the …
deterministic or chance scenarios. This chapter deals with experiments demonstrating the …
Molecular asymmetry in extraterrestrial organic chemistry: An analytical perspective
S Pizzarello, TL Groy - Geochimica et Cosmochimica Acta, 2011 - Elsevier
The enantiomeric excesses determined for eight amino acids and one hydroxy acid of
carbonaceous chondrite meteorites represent to date the only case of molecular asymmetry …
carbonaceous chondrite meteorites represent to date the only case of molecular asymmetry …
Asymmetric activation
K Mikami, M Terada, T Korenaga… - Angewandte Chemie …, 2000 - Wiley Online Library
While nonracemic catalysts can generate nonracemic products with or without the nonlinear
relationship in enantiomeric excesses between catalysts and products, racemic catalysts …
relationship in enantiomeric excesses between catalysts and products, racemic catalysts …