Spontaneous resolution, whence and whither: from enantiomorphic solids to chiral liquid crystals, monolayers and macro-and supra-molecular polymers and …

L Pérez-García, DB Amabilino - Chemical Society Reviews, 2007 - pubs.rsc.org
One of the great challenges in stereochemistry is the explanation of why some molecules
resolve spontaneously while others do not. In this critical review the recent advances in the …

Chirality in adsorption on solid surfaces

F Zaera - Chemical Society Reviews, 2017 - pubs.rsc.org
In the present review we survey the main advances made in recent years on the
understanding of chemical chirality at solid surfaces. Chirality is an important topic, made …

Visible circularly polarized luminescence of octanuclear circular Eu (III) helicate

YB Tan, Y Okayasu, S Katao, Y Nishikawa… - Journal of the …, 2020 - ACS Publications
This work reports on the structural and photophysical characterization of D 4-symmetrical
octanuclear circular LnIII helicates,[(R)-or (S)-iPr-Pybox] 8 (LnIII) 8 (THP) 8 (where Ln= Eu …

Amplification of chirality in two-dimensional enantiomorphous lattices

R Fasel, M Parschau, KH Ernst - Nature, 2006 - nature.com
The concept of chirality dates back to 1848, when Pasteur manually separated left-handed
from right-handed sodium ammonium tartrate crystals. Crystallization is still an important …

Crystalline architectures as templates of relevance to the origins of homochirality

I Weissbuch, M Lahav - Chemical Reviews, 2011 - ACS Publications
From the days of Biot1 and Pasteur, 2 when it was recognized that biopolymers are
composed from residues of a single handedness, scientists were puzzled as to the ancestry …

Enantiomer surface chemistry: conglomerate versus racemate formation on surfaces

S Dutta, AJ Gellman - Chemical Society Reviews, 2017 - pubs.rsc.org
Research on surface chirality is motivated by the need to develop functional chiral surfaces
for enantiospecific applications. While molecular chirality in 3D has been the subject of study …

Effect of molecular chirality on the morphology of biomimetic Langmuir monolayers

N Nandi, D Vollhardt - Chemical reviews, 2003 - ACS Publications
Chirality (originated from the Greek word “cheir”, meaning “hand”) is an expression of
nature, which is observed in its various forms. Traditionally, a lack of symmetry is considered …

Stochastic “mirror symmetry breaking” via self-assembly, reactivity and amplification of chirality: relevance to abiotic conditions

I Weissbuch, L Leiserowitz, M Lahav - Prebiotic Chemistry, 2005 - Springer
Theories of prebiotic life suggest that homochirality emerged in Nature in abiotic times via
deterministic or chance scenarios. This chapter deals with experiments demonstrating the …

Molecular asymmetry in extraterrestrial organic chemistry: An analytical perspective

S Pizzarello, TL Groy - Geochimica et Cosmochimica Acta, 2011 - Elsevier
The enantiomeric excesses determined for eight amino acids and one hydroxy acid of
carbonaceous chondrite meteorites represent to date the only case of molecular asymmetry …

Asymmetric activation

K Mikami, M Terada, T Korenaga… - Angewandte Chemie …, 2000 - Wiley Online Library
While nonracemic catalysts can generate nonracemic products with or without the nonlinear
relationship in enantiomeric excesses between catalysts and products, racemic catalysts …