Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and …
Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …
active and selective catalysts. Recently, C–H-active transformations using porous materials …
Single-atom catalysts across the periodic table
Isolated atoms featuring unique reactivity are at the heart of enzymatic and homogeneous
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …
Oxo dicopper anchored on carbon nitride for selective oxidation of methane
Selective conversion of methane (CH4) into value-added chemicals represents a grand
challenge for the efficient utilization of rising hydrocarbon sources. We report here dimeric …
challenge for the efficient utilization of rising hydrocarbon sources. We report here dimeric …
Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site
Natural gas, consisting mainly of methane (CH4), has a relatively low energy density at
ambient conditions (~ 36 kJ l− 1). Partial oxidation of CH4 to methanol (CH3OH) lifts the …
ambient conditions (~ 36 kJ l− 1). Partial oxidation of CH4 to methanol (CH3OH) lifts the …
Metal–organic framework-based catalysts with single metal sites
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
Atomic-level design of metalloenzyme-like active pockets in metal–organic frameworks for bioinspired catalysis
Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …
Confining isolated atoms and clusters in crystalline porous materials for catalysis
Abstract Structure–reactivity relationships for nanoparticle-based catalysts have been
greatly influenced by the study of catalytic materials with either supported isolated metal …
greatly influenced by the study of catalytic materials with either supported isolated metal …
Conceptual and practical aspects of metal–organic frameworks for solid–gas reactions
The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …
Using machine learning and data mining to leverage community knowledge for the engineering of stable metal–organic frameworks
Although the tailored metal active sites and porous architectures of MOFs hold great promise
for engineering challenges ranging from gas separations to catalysis, a lack of …
for engineering challenges ranging from gas separations to catalysis, a lack of …
Sub‐3 nm Ultrafine Cu2O for Visible Light Driven Nitrogen Fixation
Cu2O, a low‐cost, visible light responsive semiconductor photocatalyst represents an ideal
candidate for visible light driven photocatalytic reduction of N2 to NH3 from the viewpoint of …
candidate for visible light driven photocatalytic reduction of N2 to NH3 from the viewpoint of …