Multi-stimuli responsive macromolecules and their assemblies

J Zhuang, MR Gordon, J Ventura, L Li… - Chemical Society …, 2013 - pubs.rsc.org
In this review, we outline examples that illustrate the design criteria for achieving
macromolecular assemblies that incorporate a combination of two or more chemical …

[HTML][HTML] Recent advances in degradable synthetic polymers for biomedical applications‐Beyond polyesters

M Dirauf, I Muljajew, C Weber, US Schubert - Progress in Polymer Science, 2022 - Elsevier
Polyesters have been studied intensely over the last few decades and proved to be suitable
for a wide range of applications. Despite all benefits, drawbacks such as eg the acidification …

Ring-opening polymerization—an introductory review

O Nuyken, SD Pask - Polymers, 2013 - mdpi.com
This short, introductory review covers the still rapidly growing and industrially important field
of ring opening polymerization (ROP). The review is organized according to mechanism …

Chemically recyclable polyolefin-like multiblock polymers

Y Zhao, EM Rettner, KL Harry, Z Hu, J Miscall… - Science, 2023 - science.org
Polyolefins are the most important and largest volume plastics produced. Unfortunately, the
enormous use of plastics and lack of effective disposal or recycling options have created a …

Clip chemistry: diverse (bio)(macro) molecular and material function through breaking covalent bonds

P Shieh, MR Hill, W Zhang, SL Kristufek… - Chemical …, 2021 - ACS Publications
In the two decades since the introduction of the “click chemistry” concept, the toolbox of “click
reactions” has continually expanded, enabling chemists, materials scientists, and biologists …

[HTML][HTML] The ROMP toolbox upgraded

A Leitgeb, J Wappel, C Slugovc - Polymer, 2010 - Elsevier
This article features the current state of research in olefin metathesis polymerization
techniques towards the synthesis of functional polymeric materials. Emphasis is laid on work …

Preparation of biomolecule-polymer conjugates by grafting-from using ATRP, RAFT, or ROMP

MS Messina, KMM Messina, A Bhattacharya… - Progress in polymer …, 2020 - Elsevier
Biomolecule-polymer conjugates are constructs that take advantage of the functional or
otherwise beneficial traits inherent to biomolecules and combine them with synthetic …

Intramolecularly cross-linked polymers: from structure to function with applications as artificial antibodies and artificial enzymes

J Chen, ES Garcia, SC Zimmerman - Accounts of chemical …, 2020 - ACS Publications
Conspectus Cross-linking of polymers significantly alters their physical properties, greatly
expanding their everyday utility. Indeed, the polymeric networks resulting from linkages …

Direct synthesis of functionalized high‐molecular‐weight polyethylene by copolymerization of ethylene with polar monomers

S Dai, C Chen - Angewandte Chemie, 2016 - Wiley Online Library
The introduction of even a small amount of polar functional groups into polyolefins could
excise great control over important material properties. As the most direct and economic …

Enol ethers are effective monomers for ring-opening metathesis polymerization: synthesis of degradable and depolymerizable poly (2, 3-dihydrofuran)

JD Feist, Y **a - Journal of the American Chemical Society, 2019 - ACS Publications
Enol ethers are widely used as quenching reagents for Grubbs catalysts. However, we
report the surprisingly effective ring-opening metathesis polymerization (ROMP) of cyclic …