Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes

JO Zoppe, NC Ataman, P Mocny, J Wang… - Chemical …, 2017 - ACS Publications
The generation of polymer brushes by surface-initiated controlled radical polymerization (SI-
CRP) techniques has become a powerful approach to tailor the chemical and physical …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Cu (0)-mediated living radical polymerization: a versatile tool for materials synthesis

A Anastasaki, V Nikolaou, G Nurumbetov… - Chemical …, 2016 - ACS Publications
During the past decade we have witnessed the rapid development and understanding of
living radical polymerization (LRP)(or reversible deactivation radical polymerizations …

Surface-Initiated Zerovalent Metal-Mediated Controlled Radical Polymerization (SI-Mt0CRP) for Brush Engineering

D Wu, W Li, T Zhang - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus The surface-tethered polymer brush has become a powerful approach to
tailoring the chemical and physical properties of surfaces and interfaces and revealed broad …

Polymer brushes here, there, and everywhere: Recent advances in their practical applications and emerging opportunities in multiple research fields

O Azzaroni - Journal of Polymer Science Part A: Polymer …, 2012 - Wiley Online Library
Bottom‐up surface processing with well‐defined polymeric structures becomes increasingly
important in many current technologies. Polymer brushes, that is, assemblies of …

Reversible-deactivation radical polymerization in the presence of metallic copper. A critical assessment of the SARA ATRP and SET-LRP mechanisms

D Konkolewicz, Y Wang, M Zhong, P Krys… - …, 2013 - ACS Publications
Reversible-deactivation radical polymerization (RDRP) in the presence of Cu0 is a versatile
technique that can be used to create well-controlled polymers with complex architectures …

Polymer brush synthesis on surface modified carbon nanotubes via in situ emulsion polymerization

MU Khan, KR Reddy, T Snguanwongchai… - Colloid and Polymer …, 2016 - Springer
In situ emulsion polymerization was employed for synthesizing carbon nanotube (CNT)
composites in a colloidal system with poly (styrene) or PS to form nanostructured brush …

Poly(N-isopropylacrylamide) Brushes Grafted from Cellulose Nanocrystals via Surface-Initiated Single-Electron Transfer Living Radical Polymerization

JO Zoppe, Y Habibi, OJ Rojas, RA Venditti… - …, 2010 - ACS Publications
Cellulose nanocrystals (CNCs) or nanowhiskers produced from sulfuric acid hydrolysis of
ramie fibers were used as substrates for surface chemical functionalization with …

Cu (0)-mediated living radical polymerization: recent highlights and applications; a perspective

A Anastasaki, V Nikolaou, DM Haddleton - Polymer Chemistry, 2016 - pubs.rsc.org
Cu (0)-mediated living radical polymerization or single electron transfer living radical
polymerization (Cu (0)-mediated LRP or SET-LRP) is a versatile polymerization technique …

Novel Pickering emulsifiers based on pH-responsive poly (2-(diethylamino) ethyl methacrylate) latexes

AJ Morse, SP Armes, KL Thompson, D Dupin… - Langmuir, 2013 - ACS Publications
The emulsion copolymerization of 2-(diethylamino) ethyl methacrylate (DEA) with a
divinylbenzene cross-linker in the presence of monomethoxy-capped poly (ethylene glycol) …