Open-shell molecules such as radicals, carbenes, and electronically excited-state molecules
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …

Magnetism is a phenomenon that has always captured the imagination of humans. Its
discovery in the western world is attributed to the ancient Greek civilization. More than 2500 …

The development, characterization, and technological exploitation of new materials,
particularly as components in 'smart'systems, are key challenges for chemistry and physics …

This critical review is devoted to semiconducting and high spin polymers which are of great
scientific interest in view of further development of the organic electronics and the emerging …

The chemistry of nitroxide radicals in the molecular design of magnets - IOPscience This
site uses cookies. By continuing to use this site you agree to our use of cookies. To find out …

Can two isolated radical cations (polarons) exist simultaneously on a π‐conjugated chain or
do they coalesce into a single, doubly charged spinless (bipolaron) deformation? This long …

A new Kekulé polycyclic hydrocarbon with a singlet biradical index of 50% was synthesized.
The singlet biradical character was assessed with UV and 1H-NMR spectroscopy, cyclic …

We judge the energetic sequence of spin states in substituted methylenes by ab initio
multiconfigurational computations and, where feasible, density functional modeling …

Nitroxide radicals play a central role in the recent development of organomagnetic materials
or molecular-based magnetic materials. This feature article considers the recent progress in …

In agreement with the experimental results of the groups of Rassat and Iwamura on
respectively m-phenylene bis (fert-butyl nitroxides) 2 and 3, ab initio calculations on m …