Sustainability of green solvents–review and perspective

V Hessel, NN Tran, MR Asrami, QD Tran, NVD Long… - Green …, 2022 - pubs.rsc.org
Solvents define pivotal properties for chemical processing and chemical reactions, and can
be as game-changing as catalysts. A solvent can be the key to a good chemical process …

The novel contribution of non-noble metal catalysts for intensified carbon dioxide hydrogenation: Recent challenges and opportunities

M Tawalbeh, RMN Javed, A Al-Othman… - Energy Conversion and …, 2023 - Elsevier
The enormous growth in anthropologic activities (carbon dioxide (CO 2) emissions) and
continuous depletion of non-renewable sources have contributed to the problem of climate …

Heterogeneous hydroformylation of alkenes by Rh-based catalysts

B Liu, Y Wang, N Huang, X Lan, Z **e, JG Chen… - Chem, 2022 - cell.com
Heterogeneously catalyzed hydroformylation reactions avert the problems of separation in
homogeneous reactions, reduce the discharge of phosphorus-containing wastes, and …

Catalytic hydroformylation of alkenes to branched aldehydes promoted by water on Rh nanoclusters-anchored porous triphenylphosphine frameworks

D Wang, G Zeng, J Fang, H Li, H Chen, J Ma… - Chemical Engineering …, 2024 - Elsevier
The highly selective catalytic hydroformylation of alkenes to produce aldehydes is an
important reaction in the chemical industry. While the recycling of the currently used …

Operando characterization of rhodium catalyst degradation in hydroformylation

M Gerlach, F Jameel, A Seidel-Morgenstern… - Catalysis Science & …, 2023 - pubs.rsc.org
For a comprehensive understanding of catalyst stability, knowledge of deactivation
processes is an important keystone in addition to activity and selectivity. The underlying …

Solvent effect on mechanistic pathways in Rh-catalyzed hydroformylation of formaldehyde

C Yang, M Li, W Dai, J Wei, Q Yang, Y Feng, W Yang… - Molecular …, 2022 - Elsevier
The homogeneous catalytic hydroformylation of formaldehyde to glycolaldehyde is a key
intermediate step for one-step synthesis of ethylene glycol from syngas. The effect of solvent …

A comprehensive study on the steric impact of phosphine ligands on propene hydroformylation

M Zhang, H Mo, Y Chen - Molecular Catalysis, 2024 - Elsevier
This research examines the steric impact of ligand structure on Rhodium-catalyzed
hydroformylation, specifically, the significant impact of substituent positioning of …

Outlook of Cobalt-Based Catalysts for Heterogeneous Hydroformylation of Olefins: From Nanostructures to Single Atoms

W Gao, S Liu, Z Wang, J Peng, Y Zhang, X Yuan… - Energy & …, 2023 - ACS Publications
Hydroformylation of olefins, as a study of olefinic downstream derivative production, is of
great relevance in chemical production. Heterogeneous hydroformylation is beneficial for …

Bridging micro and macro scale: Deciphering the role of phosphite ligand configuration in propene hydroformylation via microkinetic and vapor-liquid equilibrium …

M Zhang, H Mo, Y Chen - Molecular Catalysis, 2024 - Elsevier
In this work, the effects of phosphite ligand structural modifications on the Rhodium-
catalyzed hydroformylation of propene were elucidated by density functional theory (DFT) …

[HTML][HTML] Mechanistic kinetic modeling of the rhodium-catalyzed tandem hydroaminomethylation of 1-decene in a thermomorphic solvent system

W Kortuz, S Kirschtowski, A Seidel-Morgenstern… - Catalysis …, 2023 - Elsevier
For a more resource-efficient production of amines the homogeneously catalyzed tandem
hydroaminomethylation reaction is of large relevance. The kinetics of the sulfoxantphos …