[HTML][HTML] A review of new developments in the Friedel–Crafts alkylation–From green chemistry to asymmetric catalysis

M Rue**, BJ Nachtsheim - Beilstein Journal of Organic …, 2010 - beilstein-journals.org
The development of efficient Friedel–Crafts alkylations of arenes and heteroarenes using
only catalytic amounts of a Lewis acid has gained much attention over the last decade. The …

Synthetic methodologies of achiral diarylmethanols, diaryl and triarylmethanes (TRAMs) and medicinal properties of diaryl and triarylmethanes-an overview

S Mondal, G Panda - RSC Advances, 2014 - pubs.rsc.org
The last decade has witnessed a high demand of various synthetic approaches towards
bioactive achiral diarylmethanols, diaryl and triarylmethanes and the molecules derived …

π-Activated alcohols: an emerging class of alkylating agents for catalytic Friedel–Crafts reactions

M Bandini, M Tragni - Organic & Biomolecular Chemistry, 2009 - pubs.rsc.org
The direct functionalization of aromatic compounds, via Friedel–Crafts alkylation reactions
with alcohols, is one of the cornerstones in organic chemistry. The present emerging area …

Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions

A Cook, SG Newman - Chemical Reviews, 2024 - ACS Publications
Alcohols are abundant and attractive feedstock molecules for organic synthesis. Many
methods for their functionalization require them to first be converted into a more activated …

A functionalized UiO-66 MOF acting as a luminescent chemosensor for selective and sensitive turn-on detection of superoxide and acetylacetone

S Ghosh, A Das, S Biswas - Microporous and Mesoporous Materials, 2021 - Elsevier
A luminescent Zr IV based UiO-66 metal-organic framework (MOF) with sulphonamide
functionality was successfully synthesized using solvothermal method and characterized …

From conventional Lewis acids to heterogeneous montmorillonite K10: eco‐friendly plant‐based catalysts used as green Lewis acids

M Hechelski, A Ghinet, B Louvel, P Dufrénoy… - …, 2018 - Wiley Online Library
The concept of green chemistry began in the USA in the 1990s. Since the publication of the
12 principles of this concept, many reactions in organic chemistry have been developed …

Organocatalyzed Friedel–Crafts arylation of benzylic alcohols

JA McCubbin, OV Krokhin - Tetrahedron Letters, 2010 - Elsevier
Electron-rich aromatic and heteroaromatic rings are functionalized directly with a variety of
benzylic alcohols under mild conditions. The reaction is catalyzed by commercially available …

A simple catalyst for the efficient benzylation of arenes by using alcohols, ethers, styrenes, aldehydes, or ketones

A Prades, R Corberán, M Poyatos… - Chemistry–A European …, 2009 - Wiley Online Library
One catalyst fits all! One catalyst is active for a wide set of benzylating reactions (see
scheme). A tandem process allows the use of aldehydes and ketones as benzylating agents …

Iron-catalyzed arene alkylation reactions with unactivated secondary alcohols

LR Jefferies, SP Cook - Organic letters, 2014 - ACS Publications
A simple, iron-based catalytic system allows for the inter-and intramolecular arylation of
unactivated secondary alcohols. This transformation expands the substrate scope beyond …

Tin exchanged heteropoly tungstate: An efficient catalyst for benzylation of arenes with benzyl alcohol

CR Kumar, KTV Rao, PSS Prasad… - Journal of Molecular …, 2011 - Elsevier
The partial exchange of tin with the protons of 12-tungstophosphoric acid (TPA) results in a
highly active heterogeneous catalyst for benzylation of arenes with benzyl alcohol as …