A comparison of RAFT and ATRP methods for controlled radical polymerization

NP Truong, GR Jones, KGE Bradford… - Nature Reviews …, 2021 - nature.com
Reversible addition–fragmentation chain-transfer (RAFT) polymerization and atom transfer
radical polymerization (ATRP) are the two most common controlled radical polymerization …

Atom transfer radical polymerization: a mechanistic perspective

F Lorandi, M Fantin… - Journal of the American …, 2022 - ACS Publications
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …

Bottlebrush polymers: From controlled synthesis, self-assembly, properties to applications

Z Li, M Tang, S Liang, M Zhang, GM Biesold… - Progress in Polymer …, 2021 - Elsevier
Bottlebrush polymers (BBPs) have emerged as intriguing class of materials for an array of
applications, including supersoft elastomers, organic optoelectronics, templates for crafting …

Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering

YN Zhou, JJ Li, TT Wang, YY Wu, ZH Luo - Progress in Polymer Science, 2022 - Elsevier
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …

Toward green atom transfer radical polymerization: current status and future challenges

S Dworakowska, F Lorandi, A Gorczyński… - Advanced …, 2022 - Wiley Online Library
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …

Molecular bottlebrushes as novel materials

G **e, MR Martinez, M Olszewski, SS Sheiko… - …, 2018 - ACS Publications
Molecular bottlebrushes are building blocks for the design of unique polymeric materials
whose physical properties are fundamentally governed by their densely grafted structures …

Atom transfer radical polymerization: billion times more active catalysts and new initiation systems

TG Ribelli, F Lorandi, M Fantin… - Macromolecular rapid …, 2019 - Wiley Online Library
Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …

Radical polymerization of acrylates, methacrylates, and styrene: Biobased approaches, mechanism, kinetics, secondary reactions, and modeling

T Pirman, M Ocepek, B Likozar - Industrial & Engineering …, 2021 - ACS Publications
Biobased polymer molecules are a goal for the future. Here, the different intermediate
pathways toward renewable structural constituents, which can substitute petrochemically …

Radical polymerization of acrylic monomers: An overview

N Ballard, JM Asua - Progress in Polymer Science, 2018 - Elsevier
Since their discovery and development in the 20th century, acrylic polymers have become
an integral part of numerous industries and are used in a myriad of applications. As is true …

Synthesis and characterization of the most active copper ATRP catalyst based on tris [(4-dimethylaminopyridyl) methyl] amine

TG Ribelli, M Fantin, JC Daran… - Journal of the …, 2018 - ACS Publications
The tris [(4-dimethylaminopyridyl) methyl] amine (TPMANMe2) as a ligand for copper-
catalyzed atom transfer radical polymerization (ATRP) is reported. In solution, the [CuI …