Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Octacyanidometallates for multifunctional molecule-based materials

S Chorazy, JJ Zakrzewski, M Magott… - Chemical Society …, 2020 - pubs.rsc.org
Octacyanidometallates have been successfully employed in the design of heterometallic
coordination systems offering a spectacular range of desired physical properties with great …

Synthesis of 3d Metallic Single-Molecule Magnets

G Aromí, EK Brechin - Single-molecule magnets and related phenomena, 2006 - Springer
The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

Molecular magnetic materials based on 4d and 5d transition metals

XY Wang, C Avendaño, KR Dunbar - Chemical Society Reviews, 2011 - pubs.rsc.org
The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …

Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets

JH Wang, ZY Li, M Yamashita, XH Bu - Coordination Chemistry Reviews, 2021 - Elsevier
Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …

Structural and functional evolution of metallacrowns

G Mezei, CM Zaleski, VL Pecoraro - Chemical reviews, 2007 - ACS Publications
In 1967 Pederson reported the synthesis of macrocyclic crown ethers and their ability to
selectively bind alkali and alkaline earth ions, 1, 2 and since then supramolecular …

Slow relaxation processes and single-ion magnetic behaviors in dysprosium-containing complexes

Y Wang, XL Li, TW Wang, Y Song, XZ You - Inorganic chemistry, 2010 - ACS Publications
A series of one-dimensional complexes [Ln (L1) 3 (HOCH2CH2OH)] n (L1= 2-furoate anion;
Ln= Nd (1), Sm (2), Gd (3), Tb (4), Dy (5), Er (6)) have been synthesized. The complexes …

[PDF][PDF] A single-molecule-magnetic, cubane-based, triangular Co12 supercluster

MH Zeng, MX Yao, H Liang, WX Zhang… - … EDITION IN ENGLISH-, 2007 - labxing.com
For single-molecule magnet (SMM) behavior, molecular clusters require Ising
magnetoanisotropy (Dmol< 0) and a large ground-state spin multiplicity.[1] These …

The impact of ligands upon topology and functionality of octacyanidometallate-based assemblies

B Nowicka, T Korzeniak, O Stefańczyk… - Coordination Chemistry …, 2012 - Elsevier
Complete overview of octacyanidometallate polymetallic assemblies is presented from a
novel viewpoint of the importance of incorporated ligands. The ligands are classified …

Coordination complexes of 15-membered pentadentate aza, oxoaza and thiaaza Schiff base macrocycles “Old Complexes Offer New Attractions”

EL Gavey, M Pilkington - Coordination Chemistry Reviews, 2015 - Elsevier
Two classes of complexes of 15-membered Schiff base macrocycles with a pentadentate (N
3 X 2) cavity (where X= O, N, S) prepared via a metal templated condensation reaction …