Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …

The design and construction of high-nuclear polyoxometalate (POM) clusters remain a
severe challenge, but attract significant interest on account of their impressive structural …

The hierarchical aggregation of molecular nanostructures from multiple components is a
grand synthetic challenge, which requires highly selective linkage control. We demonstrate …

Polyoxometalates (POMs) are discrete anionic metaloxygen clusters which can be regarded
as soluble oxide fragments. They exhibit a great diversity of sizes, nuclearities, and shapes …

Gigantic coordination molecules assembled from a large number of metal ions and organic
ligands are structurally and functionally challenging to characterize. Here we show that a …

Functionalization via covalent grafting of organic functions allows to tune the redox and acid–
base properties, and the solubility of polyoxometalates, to enhance their stability and …

Abstract A protein‐sized (ca. 4.2× 4.2× 3.6 nm3) non‐biologically derived molecule
{Nb288O768 (OH) 48 (CO3) 12}(Nb288) containing up to 288 niobium atoms has been …

Polyoxometalates (POMs) are anionic metal oxide clusters with a wide structural variety and
interesting properties,[1] and have potential applications in diverse areas such as catalysis …

The hydrothermal reactions of trivacant Keggin A‐α‐XW9O34 polyoxoanions (X= PV/SiIV)
with transition‐metal ions (NiII/CuII/FeII) in the presence of amines result in eight novel high …

The function‐oriented synthesis of polyoxometalate (POM) nanoclusters has become an
increasingly important area of research. Herein, the well‐known broad‐spectrum anticancer …