Stimulated Raman scattering: from bulk to nano

RC Prince, RR Frontiera, EO Potma - Chemical reviews, 2017 - ACS Publications
Stimulated Raman scattering (SRS) describes a family of techniques first discovered and
developed in the 1960s. Whereas the nascent history of the technique is parallel to that of …

Detecting mid-infrared light by molecular frequency upconversion in dual-wavelength nanoantennas

A Xomalis, X Zheng, R Chikkaraddy, Z Koczor-Benda… - Science, 2021 - science.org
Coherent interconversion of signals between optical and mechanical domains is enabled by
optomechanical interactions. Extreme light-matter coupling produced by confining light to …

Toward a mechanistic understanding of plasmon-mediated photocatalysis

JL Brooks, CL Warkentin, D Saha, EL Keller… - …, 2018 - degruyter.com
One of the most exciting new developments in the plasmonic nanomaterials field is the
discovery of their ability to mediate a number of photocatalytic reactions. Since the initial …

Roadmap on plasmonics

MI Stockman, K Kneipp, SI Bozhevolnyi, S Saha… - Journal of …, 2018 - iopscience.iop.org
Plasmonics is a rapidly develo** field at the boundary of physical optics and condensed
matter physics. It studies phenomena induced by and associated with surface plasmons …

Pulsed molecular optomechanics in plasmonic nanocavities: from nonlinear vibrational instabilities to bond-breaking

A Lombardi, MK Schmidt, L Weller, WM Deacon… - Physical Review X, 2018 - APS
Small numbers of surface-bound molecules are shown to behave as would be expected for
optomechanical oscillators placed inside plasmonic nanocavities that support extreme …

Giant optomechanical spring effect in plasmonic nano-and picocavities probed by surface-enhanced Raman scattering

LA Jakob, WM Deacon, Y Zhang, B de Nijs… - Nature …, 2023 - nature.com
Molecular vibrations couple to visible light only weakly, have small mutual interactions, and
hence are often ignored for non-linear optics. Here we show the extreme confinement …

Conformational contrast of surface-mediated molecular switches yields Ångstrom-scale spatial resolution in ultrahigh vacuum tip-enhanced Raman spectroscopy

N Chiang, X Chen, G Goubert, DV Chulhai, X Chen… - Nano …, 2016 - ACS Publications
Tip-enhanced Raman spectroscopy (TERS) combines the ability of scanning probe
microscopy (SPM) to resolve atomic-scale surface features with the single-molecule …

Tip-enhanced Raman spectromicroscopy on the angstrom scale: bare and CO-terminated Ag tips

N Tallarida, J Lee, VA Apkarian - ACS nano, 2017 - ACS Publications
The tip is key to the successful execution of tip-enhanced Raman scattering (TERS)
measurements in the single molecule limit. We show that nanoscopically smooth silver tips …

Many-body state description of single-molecule electroluminescence driven by a scanning tunneling microscope

K Miwa, H Imada, M Imai-Imada, K Kimura… - Nano …, 2019 - ACS Publications
Electron transport and optical properties of a single molecule in contact with conductive
materials have attracted considerable attention because of their scientific importance and …

Observation of single molecule plasmon-driven electron transfer in isotopically edited 4, 4′-bipyridine gold nanosphere oligomers

EA Sprague-Klein, MO McAnally… - Journal of the …, 2017 - ACS Publications
We clarify mechanistic questions regarding plasmon-driven chemistry and nanoscale
photocatalysis within optically confined near-field plasmonic systems. Using surface …