Insights into the solvation chemistry in liquid electrolytes for lithium-based rechargeable batteries

P **ao, X Yun, Y Chen, X Guo, P Gao, G Zhou… - Chemical Society …, 2023 - pubs.rsc.org
Lithium-based rechargeable batteries have dominated the energy storage field and attracted
considerable research interest due to their excellent electrochemical performance. As …

[HTML][HTML] Quasi-compensatory effect in emerging anode-free lithium batteries

P Li, H Kim, J Ming, HG Jung, I Belharouak, YK Sun - EScience, 2021 - Elsevier
As electric vehicle (EV) sales grew approximately 50% year-over-year, surpassing 3.2
million units in 2020, the “roaring era” of EV is around the corner. To meet the increasing …

Reforming the uniformity of solid electrolyte interphase by nanoscale structure regulation for stable lithium metal batteries

QK Zhang, SY Sun, MY Zhou, LP Hou… - Angewandte …, 2023 - Wiley Online Library
The stability of high‐energy‐density lithium metal batteries depends on the uniformity of
solid electrolyte interphase (SEI) on lithium metal anodes. Rationally improving SEI …

Electrolyte design enabling a high‐safety and high‐performance si anode with a tailored electrode–electrolyte interphase

Z Cao, X Zheng, Q Qu, Y Huang… - Advanced Materials, 2021 - Wiley Online Library
Silicon (Si) anodes are advantageous for application in lithium‐ion batteries in terms of their
high theoretical capacity (4200 mAh g− 1), appropriate operating voltage (< 0.4 V vs Li/Li+) …

[HTML][HTML] Deciphering and modulating energetics of solvation structure enables aggressive high-voltage chemistry of Li metal batteries

Z Wu, R Li, S Zhang, T Deng, H Zhang, R Zhang, J Liu… - Chem, 2023 - cell.com
The stability of localized high-concentrated electrolytes (LHCEs) on the Li metal anode has
been well established, but the understanding of its oxidation chemistry for high-voltage …

Rational design of fluorinated electrolytes for low temperature lithium‐ion batteries

DJ Yoo, Q Liu, O Cohen, M Kim… - Advanced Energy …, 2023 - Wiley Online Library
Nonaqueous carbonate electrolytes are commonly used in commercial lithium‐ion battery
(LIB). However, the sluggish Li+ diffusivity and high interfacial charge transfer resistance at …

A temperature-dependent solvating electrolyte for wide-temperature and fast-charging lithium metal batteries

M Fang, X Yue, Y Dong, Y Chen, Z Liang - Joule, 2024 - cell.com
High safety and stable wide-temperature operation are essential for lithium metal batteries
(LMBs). Herein, we designed an amide-based eutectic electrolyte composed of N-methyl-2 …

An in-situ polymerization strategy for gel polymer electrolyte Si|| Ni-rich lithium-ion batteries

M Bai, X Tang, M Zhang, H Wang, Z Wang… - Nature …, 2024 - nature.com
Coupling the Si-based anodes with nickel-rich LiNixMnyCo1− x− yO2 cathodes (x≥ 0.8) in
the energy-dense cell prototype suffers from the mechanical instability of the Li-Si alloys …

Stable operation of lithium metal batteries with aggressive cathode chemistries at 4.9 V

Z Piao, HR Ren, G Lu, K Jia, J Tan, X Wu… - Angewandte …, 2023 - Wiley Online Library
High‐voltage lithium metal batteries (LMBs) pose severe challenges for the matching of
electrolytes with aggressive electrodes, especially at low temperatures. Here, we report a …

[PDF][PDF] Restraining the escape of lattice oxygen enables superior cyclic performance towards high-voltage Ni-rich cathodes

H Yu, H Zhu, H Jiang, X Su, Y Hu… - National Science …, 2023 - academic.oup.com
Layered Ni-rich cathodes, operating at high voltage with superior cyclic performance, are
required to develop future high-energy Li-ion batteries. However, the worst lattice oxygen …