Remolding and deconstruction of industrial thermosets via carboxylic acid-catalyzed bifunctional silyl ether exchange

KEL Husted, CM Brown, P Shieh… - Journal of the …, 2023 - ACS Publications
Convenient strategies for the deconstruction and reprocessing of thermosets could improve
the circularity of these materials, but most approaches developed to date do not involve …

Phosphorus and Silicon‐Based Macromolecules as Degradable Biomedical Polymers

S Haudum, P Strasser… - Macromolecular …, 2023 - Wiley Online Library
Synthetic polymers are indispensable in biomedical applications because they can be
fabricated with consistent and reproducible properties, facile scalability, and customizable …

Applications of Biodegradable Polymers in the Encapsulation of Anticancer Metal Complexes

M Redrado, Z **ao, K Upitak, BT Doan… - Advanced Functional …, 2024 - Wiley Online Library
Metal complexes have recently attracted a lot of attention, particularly as anticancer and
antibacterial agents, owing to their versatile mechanisms and easily tunable characteristics …

Highly efficient synthesis of poly (silylether) s: Access to degradable polymers from renewable resources

H Fouilloux, MN Rager, P Ríos, S Conejero… - Angewandte …, 2022 - Wiley Online Library
The design of new materials with tunable properties and intrinsic recyclability, derived from
biomass under mild conditions, stands as a gold standard in polymer chemistry. Reported …

Thiol-triggered deconstruction of bifunctional silyl ether terpolymers via an SN Ar-triggered cascade

CM Brown, KEL Husted, Y Wang, LJ Kilgallon… - Chemical …, 2023 - pubs.rsc.org
While Si-containing polymers can often be deconstructed using chemical triggers such as
fluoride, acids, and bases, they are resistant to cleavage by mild reagents such as biological …

Amino acid-based polyphosphorodiamidates with hydrolytically labile bonds for degradation-tuned photopolymers

S Haudum, S Lenhart, SM Müller, D Tupe… - ACS Macro …, 2023 - ACS Publications
Photochemical additive manufacturing technologies can produce complex geometries in
short production times and thus have considerable potential as a tool to fabricate medical …

Creating Well-Defined monolayers of phosphine linkers incorporating ethoxysilyl groups on silica surfaces for superior immobilized catalysts

E Shakeri, J Blümel - Applied Surface Science, 2023 - Elsevier
Many applications of catalysts immobilized on solid supports like silica via bifunctional
phosphine linkers are still hampered by their decomposition, leaching, agglomeration, and …

Poly (silyl ether) s as Degradable and Sustainable Materials: Synthesis and Applications

V Zotov, S Vijjamarri, SD Mousavi, G Du - Molecules, 2024 - mdpi.com
Polymer research is currently focused on sustainable and degradable polymers which are
cheap, easy to synthesize, and environmentally friendly. Silicon-based polymers are …

Metal-free synthesis of alternating silylether–carbosilane copolymers using unsaturated ketones

N Yoshida, H Zhu, M Mitsuishi - Polymer Chemistry, 2024 - pubs.rsc.org
We report metal-free B (C6F5) 3-catalysed hydrosilylation polymerization for alternating
silylether–carbosilane copolymers. The reaction was carried out at room temperature using …

Iron‐Catalyzed Alkoxylation, Dehydrogenative‐Polymerization and Tandem Hydrosilylative‐Alkoxylation

A Sen, R Kumar, T Tewari, RG Gonnade… - … A European Journal, 2023 - Wiley Online Library
Alkoxylation, hydrosilylative‐alkoxylation, and dehydrogenative‐polymerization are some of
the most widely used transformations in synthetic chemistry. However, these transformations …