Single-atom catalysts based on the metal–oxide interaction

R Lang, X Du, Y Huang, X Jiang, Q Zhang… - Chemical …, 2020 - ACS Publications
Metal atoms dispersed on the oxide supports constitute a large category of single-atom
catalysts. In this review, oxide supported single-atom catalysts are discussed about their …

Local Structure and Coordination Define Adsorption in a Model Ir1/Fe3O4 Single‐Atom Catalyst

Z Jakub, J Hulva, M Meier, R Bliem… - Angewandte Chemie …, 2019 - Wiley Online Library
Single‐atom catalysts (SACs) bridge homo‐and heterogeneous catalysis because the active
site is a metal atom coordinated to surface ligands. The local binding environment of the …

Unraveling CO adsorption on model single-atom catalysts

J Hulva, M Meier, R Bliem, Z Jakub, F Kraushofer… - Science, 2021 - science.org
Understanding how the local environment of a “single-atom” catalyst affects stability and
reactivity remains a challenge. We present an in-depth study of copper1, silver1, gold1 …

Tailoring interfacial electron redistribution of Ni/Fe3O4 electrocatalysts for superior overall water splitting

W Xu, W Zhong, C Yang, R Zhao, J Wu, X Li… - Journal of Energy …, 2022 - Elsevier
Exploring highly active earth-abundant bifunctional electrocatalysts for water splitting at a
high output is essential for the forthcoming hydrogen economy. Non-noble Fe 3 O 4 catalyst …

Improving the Oxygen Evolution Reaction on Fe3O4(001) with Single-Atom Catalysts

E Bianchetti, D Perilli, C Di Valentin - ACS catalysis, 2023 - ACS Publications
Do** magnetite surfaces with transition-metal atoms is a promising strategy to improve the
catalytic performance toward the oxygen evolution reaction (OER), which governs the …

Single-atom catalysis: How structure influences catalytic performance

GS Parkinson - Catalysis letters, 2019 - Springer
It now seems clear that supported metal adatoms can be effective catalysts for some
reactions, but how to make best use of this phenomenon remains an open question. Most …

Magnetite incorporated amine-functional SiO2 support for bimetallic Cu-Ni alloy nanoparticles produced highly effective nanocatalyst

MZ Sarker, MM Rahman, H Minami, T Suzuki… - Colloids and Surfaces A …, 2022 - Elsevier
In this article, inclusion of iron oxide (Fe 3 O 4) in amine functional silica (SiO 2-NH 2)
support is attempted to see any improvement in catalytic property for anchored bimetallic Cu …

Adsorbate-induced structural evolution changes the mechanism of CO oxidation on a Rh/Fe 3 O 4 (001) model catalyst

Z Jakub, J Hulva, PTP Ryan, DA Duncan, DJ Payne… - Nanoscale, 2020 - pubs.rsc.org
The structure of a catalyst often changes in reactive environments, and following the
structural evolution is crucial for the identification of the catalyst's active phase and reaction …

Nanostructured Iron Oxides for Heterogeneous Catalysis

D Zhou, Y Zhou, Y Li, W Shen - EnergyChem, 2024 - Elsevier
Modulating the shape and crystal-phase of nano-sized iron-oxide particles play an essential
role in the design of highly efficient heterogeneous catalysts. Iron oxides usually present as …

Adatom Bonding Sites in a Nickel‐Fe3O4(001) Single‐Atom Model Catalyst and O2 Reactivity Unveiled by Surface Action Spectroscopy with Infrared Free‐Electron …

Y Liu, Z Han, S Gewinner, W Schöllkopf… - Angewandte Chemie …, 2022 - Wiley Online Library
Single‐atom (SA) catalysis presently receives much attention with its promise to decrease
the cost of the active material while increasing the catalyst's performance. However, key …