Catalytic tandem dehydrochlorination–hydrogenation of PVC towards valorisation of chlorinated plastic waste

G O'Rourke, T Hennebel, M Stalpaert, A Skorynina… - Chemical …, 2023 - pubs.rsc.org
Chemical treatment of end-of-life PVC at high temperature often results in the formation of
polyacetylene and eventually aromatic char. These insoluble conjugated polymers lead to …

High-Quality In Situ X-ray Absorption Spectroscopy Monitoring of the Palladium Nucleation inside the 3D Printed Microfluidic Chip

AV Dobrovolskaya, SV Chapek… - The Journal of …, 2023 - ACS Publications
An efficient approach for high-quality X-ray absorption spectroscopy (XAS) measurements is
proposed and exemplified by monitoring the nucleation of palladium nanoparticles from Pd …

In situ X-ray absorption spectroscopy cells for high pressure homogeneous catalysis

PV Shvets, PA Prokopovich, AI Dolgoborodov… - Catalysts, 2022 - mdpi.com
We have designed, built, and tested two cells for in situ and, potentially, operando X-ray
absorption spectroscopy experiments in transmission and fluorescence modes. The cells …

[HTML][HTML] In situ photodeposition of ultra-small palladium particles on TiO2

E Kozyr, S Martí-Sánchez, A Skorynina… - Synchrotron …, 2024 - journals.iucr.org
In situ and operando investigation of photocatalysts plays a fundamental role in
understanding the processes of active phase formation and the mechanisms of catalytic …

Reductive Cross-Electrophile C(sp2)–C(sp3) Coupling Catalyzed by PtI2: In Situ Structural Determination of the Intermediates by X-ray Absorption Spectroscopy …

TV Krasnyakova, DV Nikitenko, AS Gogil'chin… - …, 2023 - ACS Publications
The reductive cross-electrophile coupling, enabling direct binding of carbon electrophiles,
has many benefits over conventional cross-coupling methods that require a carbon …

Catalyst‐Green Solvent System for Highly Efficient Production of Carboxylic Acids from Light Oxygenates, CO2 and H2

Y Wang, Y Zhang, Y Wang, L Zhang, J He… - …, 2024 - Wiley Online Library
Catalytic hydrogenation of carbon dioxide (CO2) for the preparation of higher carboxylic
acids is attractive and promising. Herein, we demonstrate a general strategy for producing …

[PDF][PDF] Tracking active sites in metal-TiO2 systems for photocatalytic H2 production by in situ and operando spectroscopies

E Kozyr - 2024 - iris.unito.it
Photocatalytic hydrogen (H₂) production represents a promising pathway for sustainable
energy generation by using solar energy to drive water splitting reactions. Metal-TiO₂ …