This article reviews recent work in the area of non-innocent behaviour in polynuclear metal
complexes. Non-innocence, which occurs when metal-based and ligand-based redox …

Since the discovery that Mn121212OAc acts as a single-molecule magnet (SMM), an
increasing number of transition metal complexes have been demonstrated to behave as …

Metallo-supramolecular AB block copolymers are the first examples of macromolecular
engineeering. A new concept for the formation of block copolymers by a supramolecular …

Heteronuclear cationic complexes, LCuLn 3+ and (LCu) 2Ln 3+, were employed as nodes in
designing high‐nuclearity complexes and coordination polymers with a rich variety of …

The known complex {Cp (PPh3) 2Ru} 2 (μ-C⋮ CC⋮ C)(3-Ph) and its PMe3-substitution
product {Cp (PPh3)(PMe3) Ru} 2 (μ-C⋮ CC⋮ C)(3-Me) have been shown by cyclic …

Single-molecule magnets (SMMs) are a class of coordination compounds that attract
attention because of their magnetic bistability.[1] These finite-size molecules show a slow …

The coordination chemistries of the triple tetradentate triplesalen ligands H6talen, H6talen t-
Bu2, and H6talenNO2 have been investigated with nickel (II). These triplesalen ligands …

Spin and conformational dynamics in symmetric alkyne-bridged multi [copper (II) porphyrin]
structures have been studied in toluene solution at variable temperature using steady-state …

The trinuclear CuII complex [(talen) CuII3](1) using the new triplesalen ligand H6talen has
been synthesized and structurally characterized. The three CuII ions are bridged in am …

[Mn3O (O2CMe) 3 (dpd) 3/2)] 2 (I3) 2 has been obtained from the reaction of 1, 3-di (pyridin-
2-yl) propane-1, 3-dione dioxime (dpdH2) with triangular [MnIII3O (O2CMe)(py) 3](ClO4). It …