Boron-Doped Molecular Carbons Bearing a Formal Boron-Inserted Pentalene: Synthesis, Electronic Structures and Properties

L Yuan, J Yang, P Lv, Y Liu, Z Li, Y Wang, C Dou - Organic Letters, 2024 - ACS Publications
Two boron-doped molecular carbons (BMCs), featuring one formal boron-inserted
pentalene (BP) embedded into the C20B or C28B polycyclic π-skeleton, were successfully …

Functionalization of Clar's Goblet Diradical with Heteroatoms: Tuning the Excited-State Energies to Promote Triplet-to-Singlet Conversion

A Derradji, ME Sandoval-Salinas, G Ricci… - The Journal of …, 2025 - ACS Publications
The ground-state spin multiplicity as well as the energy difference between the lowest-
energy spin-singlet (S 1) and spin-triplet (T 1) excited states of topologically frustrated …

2-doped tetrathia [7] helicenes: synthesis and property-change induced by “BO bond inversion”

L Menduti, C Baldoli, S Manetto, C Villani… - Organic Chemistry …, 2025 - pubs.rsc.org
Helical distortion of polyaromatic hydrocarbons gives rise to a special class of π-conjugated
systems, namely helicenes. Owing to their configurational stability and easily tunable …

Polycyclic Aromatic Hydrocarbons with a Boron‐Doped Zigzag/Armchair Topology: A Boron‐Edging Strategy for Organic Narrowband Emitters

X Tian, Z Fan, Z Li, S Zhang, Z Li, X Zhuang… - Angewandte Chemie … - Wiley Online Library
Control over molecular topologies and/or heteroatom do** of polycyclic aromatic
hydrocarbons (PAHs) may alter their electronic structures and achieve desirable physical …

Spiro‐Fused vs 575‐Ringed Boron‐Doped Polycyclic π‐Systems: Selective Synthesis, Reactivity and Properties

Y Liu, X Tian, Z Li, T Zhang, L Yuan, Y Wang… - Angewandte Chemie … - Wiley Online Library
Incorporation of heteroatoms and/or non‐hexagonal rings into polycyclic aromatic
hydrocarbons (PAHs) can alter their intrinsic structures and physical properties. However, it …

Emission‐Tunable B← N Lewis Pair‐Functionalized Naphthalenes

Y Zhang, A Matler, J Krebs, I Krummenacher… - … –A European Journal - Wiley Online Library
Herein, we simultaneously synthesized three different double B← N Lewis pair‐
functionalized naphthalenes including the asymmetric BNNY and BNNO and the mirror …

Perturbing Pentalene: Aromaticity and Antiaromaticity in a Non‐alternant Polycyclic Aromatic Hydrocarbon and BN‐heteroanalogues

C Anstöter, PW Fowler - ChemPhysChem - Wiley Online Library
Pentalene (C8H6) and NN‐and BB‐bridged heterocyclic analogues (BN) 4H6, derived by
replacement of CC pairs with BN, are taken as paradigms for tuning of ring‐current (anti) …

Boraphenalenes

D Zhao, L Guo - Synfacts, 2024 - thieme-connect.com
Boraphenalenes Page 1 1042 © 2024. Thieme. All rights reserved. Georg Thieme Verlag KG,
Rüdigerstraße 14, 70469 Stuttgart, Germany A. IKENO, M. HAYAKAWA, M. SAKAI, Y. TSUTSUI …