Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

[PDF][PDF] The green chemistry paradigm in modern organic synthesis

SG Zlotin, KS Egorova, VP Ananikov, AA Akulov… - Russ. Chem …, 2023 - researchgate.net
After the appearance of the green chemistry concept, which was introduced in the chemistry
vocabulary in the early 1990s, its main statements have been continuously developed and …

Deciphering complexity in Pd–catalyzed cross-couplings

GE Clarke, JD Firth, LA Ledingham… - Nature …, 2024 - nature.com
Understanding complex reaction systems is critical in chemistry. While synthetic methods for
selective formation of products are sought after, oftentimes it is the full reaction signature, ie …

Sulfur in Waste‐Free Sustainable Synthesis: Advancing Carbon–Carbon Coupling Techniques

NS Shlapakov, AD Kobelev, JV Burykina… - Angewandte …, 2024 - Wiley Online Library
This review explores the pivotal role of sulfur in advancing sustainable carbon‐carbon (C−
C) coupling reactions. The unique electronic properties of sulfur, as a soft Lewis base with …

[HTML][HTML] Modified desolvation method enables simple one-step synthesis of gelatin nanoparticles from different gelatin types with any bloom values

P Khramtsov, O Burdina, S Lazarev, A Novokshonova… - Pharmaceutics, 2021 - mdpi.com
Gelatin nanoparticles found numerous applications in drug delivery, bioimaging,
immunotherapy, and vaccine development as well as in biotechnology and food science …

[HTML][HTML] On an intensification factor for green chemistry and engineering: The value of an operationally simple decision-making tool in process assessment

DF Rivas, P Cintas - Sustainable Chemistry and Pharmacy, 2022 - Elsevier
This perspective provides the conceptual basis and potentiality of a new metric in green
chemistry and engineering. Called the intensification factor (IF), as initially intended in the …

Current trends in organic chemistry: contribution of the ND Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

MP Egorov, VP Ananikov, EG Baskir… - Russian Chemical …, 2024 - Springer
A key goal of organic chemistry is to develop new principles for the control of reactions,
which can be used to create promising materials demanded in all fields of scientific research …

Fast evaluation of the safety of chemical reactions using cytotoxicity potentials and bio-Strips

KS Egorova, AV Posvyatenko, AS Galushko… - Chemosphere, 2023 - Elsevier
We introduce new quantitative environmental metrics-“cytotoxicity potentials”–which can be
used for the preliminary evaluation of the safety of chemical reactions from the viewpoint of …

Comparative assessment of heterogeneous and homogeneous Suzuki-Miyaura catalytic reactions using bio-Profiles and bio-Factors

EO Pentsak, LU Dzhemileva, VA D'yakonov… - Journal of …, 2022 - Elsevier
Transition metals are essential for most catalytic systems in fine organic synthesis. The
usage of transition metals has traditionally raised concerns about their toxicity and potential …

Integrated Toxicity Assessment of Complex Chemical Mixtures in Catalytic Reactions

AE Kolesnikov, KS Egorova, VP Ananikov - Journal of Hazardous Materials, 2025 - Elsevier
Catalytic cross-coupling reactions, such as the Mizoroki–Heck reaction, play a crucial role in
synthetic chemistry but pose significant environmental and health risks due to the toxicity of …