Searching for new chemically durable and radiation-resistant absorbent materials for
actinides and their fission products generated in the nuclear fuel cycle remain highly …

Herein we discuss the contribution of the NTB and BBP ligands in the coordination of
trivalent lanthanide ions. There is a very versatile chemistry in these two N-donor ligands …

Inspired by the uranyl‐imidazole interactions via nitrogen's (N's) of histidine residues in
single helical protein assemblies with open framework geometry that allows through …

A novel imidazole-pyridine-imidazole tri-nitrogen tridentate ligand molecule Py2IM was
designed and synthesized to act as a metal cations sensor, with the traditional terpyridyl …

The first actinide triple helices, including two supramolecular conformational isomers of
uranium (VI), have been synthesized with the aid of a flexible V-shaped ligand and a rigid …

Reaction of [UO2Cl2 (THF) 2] 2 (THF= tetrahydrofuran) with 2 equiv of HN4 (HN4= 2, 11-
diaza [3, 3](2, 6) pyridinophane) or MeN4 (MeN4= N, N′-dimethyl-2, 11-diaza [3, 3](2, 6) …

Bending the linear uranyl (UO22+) cation represents both a significant challenge and
opportunity within the field of actinide hybrid materials. As part of related efforts to engage …

The pentadentate coordination environment of a 2, 6-bis [1-[(2-hydroxyphenyl) imino] ethyl]
pyridine ligand scaffold was designed to accommodate the larger atomic radius of uranium …

Calculations performed at the density functional level of theory have been used to
investigate complexes of uranyl with the expanded porphyrin isoamethyrin and the bis …

Reaction of [Li (THF)] 4 [L](L= Me8-calix [4] pyrrole]) with 0.5 equiv of [UVIO2Cl2 (THF) 2] 2
results in formation of the oxidized calix [4] pyrrole product,[Li (THF)] 2 [LΔ](1), concomitant …