Interfaces and interphases in all-solid-state batteries with inorganic solid electrolytes

A Banerjee, X Wang, C Fang, EA Wu… - Chemical reviews, 2020 - ACS Publications
All-solid-state batteries (ASSBs) have attracted enormous attention as one of the critical
future technologies for safe and high energy batteries. With the emergence of several highly …

The passivity of lithium electrodes in liquid electrolytes for secondary batteries

X He, D Bresser, S Passerini, F Baakes… - Nature Reviews …, 2021 - nature.com
Rechargeable Li metal batteries are currently limited by safety concerns, continuous
electrolyte decomposition and rapid consumption of Li. These issues are mainly related to …

Review of emerging concepts in SEI analysis and artificial SEI membranes for lithium, sodium, and potassium metal battery anodes

W Liu, P Liu, D Mitlin - Advanced Energy Materials, 2020 - Wiley Online Library
Anodes for lithium metal batteries, sodium metal batteries, and potassium metal batteries are
susceptible to failure due to dendrite growth. This review details the structure–chemistry …

Quantifying inactive lithium in lithium metal batteries

C Fang, J Li, M Zhang, Y Zhang, F Yang, JZ Lee… - Nature, 2019 - nature.com
Lithium metal anodes offer high theoretical capacities (3,860 milliampere-hours per gram),
but rechargeable batteries built with such anodes suffer from dendrite growth and low …

Confronting the challenges in lithium anodes for lithium metal batteries

Q Wang, B Liu, Y Shen, J Wu, Z Zhao… - Advanced …, 2021 - Wiley Online Library
With the low redox potential of− 3.04 V (vs SHE) and ultrahigh theoretical capacity of 3862
mAh g− 1, lithium metal has been considered as promising anode material. However, lithium …

An inorganic‐rich solid electrolyte interphase for advanced lithium‐metal batteries in carbonate electrolytes

S Liu, X Ji, N Piao, J Chen, N Eidson… - Angewandte Chemie …, 2021 - Wiley Online Library
In carbonate electrolytes, the organic–inorganic solid electrolyte interphase (SEI) formed on
the Li‐metal anode surface is strongly bonded to Li and experiences the same volume …

Direct correlation between void formation and lithium dendrite growth in solid-state electrolytes with interlayers

V Raj, V Venturi, VR Kankanallu, B Kuiri… - Nature Materials, 2022 - nature.com
Solid-state Li-ion batteries with lithium anodes offer higher energy densities and are safer
than conventional liquid electrolyte-based Li-ion batteries. However, the growth of lithium …

Sodium metal anodes: emerging solutions to dendrite growth

B Lee, E Paek, D Mitlin, SW Lee - Chemical reviews, 2019 - ACS Publications
This comprehensive Review focuses on the key challenges and recent progress regarding
sodium-metal anodes employed in sodium-metal batteries (SMBs). The metal anode is the …

Highly fluorinated interphases enable high-voltage Li-metal batteries

X Fan, L Chen, X Ji, T Deng, S Hou, J Chen, J Zheng… - Chem, 2018 - cell.com
We were able to demonstrate excellent cycling performance of Li-metal anodes in carbonate
electrolytes by increasing the Li bis (fluorosulfonyl) imide (LiFSI) concentration to∼ 10 M …

High-energy lithium metal pouch cells with limited anode swelling and long stable cycles

C Niu, H Lee, S Chen, Q Li, J Du, W Xu, JG Zhang… - Nature Energy, 2019 - nature.com
Lithium metal anodes have attracted much attention as candidates for high-energy batteries,
but there have been few reports of long cycling behaviour, and the degradation mechanism …