Covalent organic frameworks for photocatalysis: Synthesis, structural features, fundamentals and performance

YN Gong, X Guan, HL Jiang - Coordination Chemistry Reviews, 2023 - Elsevier
Covalent organic frameworks (COFs) are a new class of crystalline porous materials
obtained from covalently attached organic building units. By virtue of the unique …

Covalent organic frameworks for energy conversion in photocatalysis

T He, Y Zhao - Angewandte Chemie International Edition, 2023 - Wiley Online Library
Intensifying energy crises and severe environmental issues have led to the discovery of
renewable energy sources, sustainable energy conversion, and storage technologies …

Computation-based regulation of excitonic effects in donor-acceptor covalent organic frameworks for enhanced photocatalysis

Y Qian, Y Han, X Zhang, G Yang, G Zhang… - Nature …, 2023 - nature.com
The strong excitonic effects widely exist in polymer-semiconductors and the large exciton
binding energy (E b) seriously limits their photocatalysis. Herein, density functional theory …

Tuning local charge distribution in multicomponent covalent organic frameworks for dramatically enhanced photocatalytic uranium extraction

H Yang, M Hao, Y **e, X Liu, Y Liu… - Angewandte Chemie …, 2023 - Wiley Online Library
Optimizing the electronic structure of covalent organic framework (COF) photocatalysts is
essential for maximizing photocatalytic activity. Herein, we report an isoreticular family of …

Engineering β-ketoamine covalent organic frameworks for photocatalytic overall water splitting

Y Yang, X Chu, HY Zhang, R Zhang, YH Liu… - Nature …, 2023 - nature.com
Covalent organic frameworks (COFs) are an emerging type of crystalline and porous
photocatalysts for hydrogen evolution, however, the overall water splitting activity of COFs is …

Promoting Solar‐driven Hydrogen Peroxide Production over Thiazole‐based Conjugated Polymers via Generating and Converting Singlet Oxygen

J Cheng, S Wan, S Cao - Angewandte Chemie International …, 2023 - Wiley Online Library
Solar‐driven synthesis of hydrogen peroxide (H2O2) from water and air provides a low‐cost
and eco‐friendly alternative route to the traditional anthraquinone method. Herein, four …

Covalent organic frameworks towards photocatalytic applications: Design principles, achievements, and opportunities

S Liu, M Wang, Y He, Q Cheng, T Qian… - Coordination Chemistry …, 2023 - Elsevier
As a subclass of porous framework materials, covalent organic frameworks (COFs) feature
permanent porosity, long-range order, and rigid backbones, and offer an important material …

Nanoscale covalent organic frameworks for enhanced photocatalytic hydrogen production

W Zhao, L Luo, M Cong, X Liu, Z Zhang, M Bahri… - Nature …, 2024 - nature.com
Nanosizing confers unique functions in materials such as graphene and quantum dots.
Here, we present two nanoscale-covalent organic frameworks (nano-COFs) that exhibit …

Efficient Photocatalytic Hydrogen Evolution by Modulating Excitonic Effects in Ni‐Intercalated Covalent Organic Frameworks

R Shen, X Li, C Qin, P Zhang… - Advanced Energy Materials, 2023 - Wiley Online Library
Covalent organic frameworks (COFs) as appealing platforms have received tremendous
interest in the field of photocatalytic H2 evolution owing to their well‐defined structures and …

Enaminone‐Linked Covalent Organic Frameworks for Boosting Photocatalytic Hydrogen Production

X Guan, Y Qian, X Zhang, HL Jiang - Angewandte Chemie, 2023 - Wiley Online Library
Covalent organic frameworks (COFs), possessing pre‐designable structures and tailorable
functionalities, are promising candidates for photocatalysis. Nevertheless, the most studied …