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Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis
Supported metal catalysts are essential to a plethora of processes in the chemical industry.
The overall performance of these catalysts depends strongly on the interaction of adsorbates …
The overall performance of these catalysts depends strongly on the interaction of adsorbates …
Controlling the Strong Metal‐Support Interaction Overlayer Structure in Pt/TiO2 Catalysts Prevents Particle Evaporation
Platinum nanoparticles (NPs) supported by titania exhibit a strong metal‐support interaction
(SMSI)[1] that can induce overlayer formation and encapsulation of the NP's with a thin layer …
(SMSI)[1] that can induce overlayer formation and encapsulation of the NP's with a thin layer …
Double-Edged Sword Effect of Classical Strong Metal–Support Interaction in Catalysts for CO2 Hydrogenation to CO, Methane, and Methanol
Y **e, J Wen, Z Li, J Chen, Q Zhang, P Ning… - ACS Materials …, 2023 - ACS Publications
Interesting phenomena such as encapsulation, charge transfer, and bond formation, etc.
induced by classical strong metal–support interaction (SMSI) during high-temperature …
induced by classical strong metal–support interaction (SMSI) during high-temperature …
Pt Molecularly Defined Precursors to Tune Particle Size and Speciation: Impact on the Reverse Water Gas Shift Reaction
Platinum-based catalysts have been largely explored for CO2 valorization by the reverse
water gas shift (RWGS) reaction, especially the Pt/TiO2 system. Understanding the distinct …
water gas shift (RWGS) reaction, especially the Pt/TiO2 system. Understanding the distinct …
[HTML][HTML] Hydrogel composites based on chitosan and CuAuTiO2 photocatalysts for hydrogen production under simulated sunlight irradiation
O Ramírez, A Lopéz-Frances, HG Baldoví… - International Journal of …, 2024 - Elsevier
This study explored the photocatalytic hydrogen evolution reaction (HER) using novel
biohydrogel composites comprising chitosan, and a photocatalyst consisting in TiO 2 P25 …
biohydrogel composites comprising chitosan, and a photocatalyst consisting in TiO 2 P25 …
Uncovering the critical function of lanthanum in CH 4 production from CO 2 using exsolved LaNiO 3 perovskite catalysts
CO2 methanation, also known as the Sabatier reaction, is of great environmental interest as
a sustainable process for energy production and storage. Herein, we report the development …
a sustainable process for energy production and storage. Herein, we report the development …
Does Cluster Encapsulation Inhibit Sintering? Stabilization of Size-Selected Pt Clusters on Fe3O4(001) by SMSI
S Kaiser, J Plansky, M Krinninger, A Shavorskiy… - ACS …, 2023 - ACS Publications
The metastability of supported metal nanoparticles limits their application in heterogeneous
catalysis at elevated temperatures due to their tendency to sinter. One strategy to overcome …
catalysis at elevated temperatures due to their tendency to sinter. One strategy to overcome …
EPR evidence of carrier effect on unpaired-electron number of Mn in SCR: The good, the bad, the ugly
Y Wang, Y Wen, Y Zhang, M Jiang, J Zhang, G Qian - Fuel, 2024 - Elsevier
Carrier plays an important role in the catalytic performance by dispersing active species and
forming strong interaction with the active species. This work compared Mn/TiO 2, Mn/Al 2 O …
forming strong interaction with the active species. This work compared Mn/TiO 2, Mn/Al 2 O …
A Critical View on the Quantification of Model Catalyst Activity
The conversion of reactants, reaction rate referred to catalyst mass, and turnover frequency
(TOF) are values typically employed to compare the activity of different catalysts. However …
(TOF) are values typically employed to compare the activity of different catalysts. However …
Interplay between geometric and electronic structures of Pt entities over TiO2 for CO oxidation
Monodispersed Pt colloids with a mean size of 2 nm were deposited uniformly on the {110}
facets of a rod-shaped rutile TiO2, forming a well-defined Pt/TiO2 system. Oxidative …
facets of a rod-shaped rutile TiO2, forming a well-defined Pt/TiO2 system. Oxidative …