Perspectives for polymer electrolytes: a view from fundamentals of ionic conductivity
We present a brief overview of current developments in the field of polymer electrolytes, with
the focus on single-ion conducting polymers. The latter have significant advantages relative …
the focus on single-ion conducting polymers. The latter have significant advantages relative …
Dilute polyelectrolyte solutions: recent progress and open questions
Polyelectrolytes are a class of polymers possessing ionic groups on their repeating units.
Since counterions can dissociate from the polymer backbone, polyelectrolyte chains are …
Since counterions can dissociate from the polymer backbone, polyelectrolyte chains are …
Fundamental limitations of ionic conductivity in polymerized ionic liquids
We present detailed studies of ionic conductivity in several polymerized ionic liquids
(PolyILs) with different size of mobile ions. Presented analysis revealed that charge diffusion …
(PolyILs) with different size of mobile ions. Presented analysis revealed that charge diffusion …
Polarization of ionic liquid and polymer and its implications for polymerized ionic liquids: An overview towards a new theory and simulation
Ionic liquid (IL)‐containing polymers garner attention for electrochemical applications. This
article overviews recent experimental and theoretical studies of polymer electrolytes that …
article overviews recent experimental and theoretical studies of polymer electrolytes that …
The role of backbone polarity on aggregation and conduction of ions in polymer electrolytes
The usual understanding in polymer electrolyte design is that an increase in the polymer
dielectric constant results in reduced ion aggregation and therefore increased ionic …
dielectric constant results in reduced ion aggregation and therefore increased ionic …
Mechanisms Controlling the Energy Barrier for Ion Hop** in Polymer Electrolytes
The present work studies the mechanisms controlling the energy barrier for ion hop** in
conducting polymers. Polymer electrolytes usually show Arrhenius-like temperature …
conducting polymers. Polymer electrolytes usually show Arrhenius-like temperature …
Mechanisms underlying ion transport in polymerized ionic liquids
We report the results of atomistic molecular dynamics simulations informed by quantum-
mechanically parametrized force fields, which identify the mechanisms underlying ion …
mechanically parametrized force fields, which identify the mechanisms underlying ion …
Effect of molecular weight on the ion transport mechanism in polymerized ionic liquids
The unique properties of ionic liquids (ILs) have made them promising candidates for
electrochemical applications. Polymerization of the corresponding ILs results in a new class …
electrochemical applications. Polymerization of the corresponding ILs results in a new class …
Ion conduction in polymerized ionic liquids with different pendant groups
Polymerized ionic liquids (PolyILs) are promising candidates for energy storage and
electrochemical devices applications. Understanding their ionic transport mechanism is the …
electrochemical devices applications. Understanding their ionic transport mechanism is the …
Mechanism of conductivity relaxation in liquid and polymeric electrolytes: Direct link between conductivity and diffusivity
Combining broadband impedance spectroscopy, differential scanning calorimetry, and
nuclear magnetic resonance we analyzed charge and mass transport in two polymerized …
nuclear magnetic resonance we analyzed charge and mass transport in two polymerized …