Validation of the CoGEF method as a predictive tool for polymer mechanochemistry
The development of force-responsive molecules called mechanophores is a central
component of the field of polymer mechanochemistry. Mechanophores enable the design …
component of the field of polymer mechanochemistry. Mechanophores enable the design …
Reaction cascades in polymer mechanochemistry
This review summarizes the development of polymer mechanochemistry-enabled reaction
cascades. According to different functions or purposes, we categorize the reported reaction …
cascades. According to different functions or purposes, we categorize the reported reaction …
Aerobic mechanochemical reversible-deactivation radical polymerization
Polymer materials suffer mechano-oxidative deterioration or degradation in the presence of
molecular oxygen and mechanical forces. In contrast, aerobic biological activities combined …
molecular oxygen and mechanical forces. In contrast, aerobic biological activities combined …
Segmented polyurethane elastomers with mechanochromic and self‐strengthening functions
K Seshimo, H Sakai, T Watabe, D Aoki… - Angewandte Chemie …, 2021 - Wiley Online Library
Mechanochromic elastomers that exhibit force‐induced cross‐linking reactions in the bulk
state are introduced. The synthesis of segmented polyurethanes (SPUs) that contain …
state are introduced. The synthesis of segmented polyurethanes (SPUs) that contain …
Self-strengthening, self-welding, shape memory, and recyclable polybutadiene-based material driven by dual-dynamic units
Y Yang, L Huang, R Wu, Z Niu, W Fan… - … Applied Materials & …, 2022 - ACS Publications
A covalent adaptable network can endow rubber materials with recyclability and
reprocessability and is expected to alleviate black pollution caused by end-of-life rubber …
reprocessability and is expected to alleviate black pollution caused by end-of-life rubber …
[HTML][HTML] Phototriggered structures: Latest advances in biomedical applications
Non-invasive control of the drug molecules accessibility is a key issue in improving
diagnostic and therapeutic procedures. Some studies have explored the spatiotemporal …
diagnostic and therapeutic procedures. Some studies have explored the spatiotemporal …
Anthracene-based mechanophores for compression-activated fluorescence in polymeric networks
The recent attention given to functionalities that respond to mechanical force has led to a
deeper understanding of force transduction and mechanical wear in polymeric materials …
deeper understanding of force transduction and mechanical wear in polymeric materials …
A mechanochemical reaction cascade for controlling load‐strengthening of a mechanochromic polymer
Y Pan, H Zhang, P Xu, Y Tian, C Wang… - Angewandte …, 2020 - Wiley Online Library
We demonstrate an intermolecular reaction cascade to control the force which triggers
crosslinking of a mechanochromic polymer of spirothiopyran (STP). Mechanochromism …
crosslinking of a mechanochromic polymer of spirothiopyran (STP). Mechanochromism …
Mechanochemistry of cationic cobaltocenium mechanophore
Recent research on the mechanochemistry of metallocene mechanophores has shed light
on the force-responsiveness of these thermally and chemically stable organometallic …
on the force-responsiveness of these thermally and chemically stable organometallic …
Enhancement of mechanophore activation in mechanochromic dendrimers by functionalization of their surface
T Watabe, D Aoki, H Otsuka - Macromolecules, 2021 - ACS Publications
The mechanochemical reactions of a series of dendrimers with a mechanochromic core
were systematically investigated, and drastic enhancement of their reactivity was observed …
were systematically investigated, and drastic enhancement of their reactivity was observed …