Multimetallic catalysis based on heterometallic complexes and clusters

P Buchwalter, J Rosé, P Braunstein - Chemical reviews, 2015 - ACS Publications
Multimetallic catalysis is based on the combined action of different metals in a chemical
transformation. It has witnessed rapidly increasing developments during the past decades in …

New trends in oxidative functionalization of carbon–hydrogen bonds: A review

GB Shul'pin - Catalysts, 2016 - mdpi.com
This review describes new reactions catalyzed by recently discovered types of metal
complexes and catalytic systems (catalyst+ co-catalyst). Works of recent years (mainly 2010 …

Supported gold nanoparticles as catalysts for the oxidation of alcohols and alkanes

SAC Carabineiro - Frontiers in Chemistry, 2019 - frontiersin.org
Supporting gold nanoparticles have shown to be extremely active for many industrially
important reactions, including oxidations. Two representative examples are the oxidation of …

Homo-and heterometallic polynuclear transition metal catalysts for alkane CH bonds oxidative functionalization: Recent advances

DS Nesterov, OV Nesterova, AJL Pombeiro - Coordination Chemistry …, 2018 - Elsevier
Polynuclear homo-and heterometallic complexes of transition metals constitute a broad
class of coordination compounds with recognized applications in catalysis, and polymetallic …

C–H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity

GB Shul'pin - Dalton Transactions, 2013 - pubs.rsc.org
This brief essay consists of a few “exciting stories” devoted to relations within a metal-
complex catalyst between a metal ion and a coordinated ligand. When, as in the case of a …

Pyrazinecarboxylic acid and analogs: Highly efficient co-catalysts in the metal-complex-catalyzed oxidation of organic compounds

AM Kirillov, GB Shul'pin - Coordination Chemistry Reviews, 2013 - Elsevier
The development of new metal complex catalysts and efficient protocols for the mild and
selective oxidation of alkanes, arenes, olefins, alcohols, and other organic substrates is a …

Cage-like Cu5Cs4-Phenylsilsesquioxanes: Synthesis, Supramolecular Structures, and Catalytic Activity

AN Bilyachenko, IS Arteev, VN Khrustalev… - Inorganic …, 2023 - ACS Publications
A small family of nonanuclear Cu5Cs4-based phenylsilsesquioxanes 1–2 were prepared by
a convenient self-assembly approach and characterized by X-ray diffraction studies. The …

Synthesis, spectroscopic studies, and single‐crystal structures of two 3‐D supramolecular zinc (II) and nickel (II) complexes containing thiazole ring: Antimicrobial …

CG Li, HL An, LQ Chai - Applied Organometallic Chemistry, 2023 - Wiley Online Library
Two novel complexes [Zn (L) 2·(NO3) 2](1) and [Ni (L) 2· 2H2O]· 2CH3OH·(NO3) 2 (2)(L= 2‐
(2‐thiazolyl)‐4‐methyl‐1, 2‐dihydroquinazoline‐N3‐oxide) were synthesized successfully …

Metal ion induced changes in the structure of Schiff base hydrazone chelates and their reactivity effect on catalytic benzyl alcohol oxidation and biological assays

MSS Adam, OS Abdel-Rahman… - Journal of Molecular …, 2023 - Elsevier
Divalent para-magnetic copper (II) and iron (II) chelates of Schiff base isatin hydrazone
derivative are synthesized and characterized, as CuLONOCl and Fe (LONO) 2, respectively …

Non‐Heme Imine‐Based Iron Complexes as Catalysts for Oxidative Processes

G Olivo, O Lanzalunga… - Advanced Synthesis & …, 2016 - Wiley Online Library
Non‐heme iron complexes are emerging as powerful and versatile catalysts in several
oxidative transformations. The most investigated iron complex structures are based on …